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From 0 to II in One‐Electron Steps: A Series of Ruthenium Complexes Supported by TropPPh2

Overview of attention for article published in Angewandte Chemie. International Edition, August 2016
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Title
From 0 to II in One‐Electron Steps: A Series of Ruthenium Complexes Supported by TropPPh2
Published in
Angewandte Chemie. International Edition, August 2016
DOI 10.1002/anie.201605687
Pubmed ID
Authors

Xiuxiu Yang, Thomas L. Gianetti, Joshua Harbort, Michael D. Wörle, Lilin Tan, Cheng‐Yong Su, Pascal Jurt, Jeffrey R. Harmer, Hansjörg Grützmacher

Abstract

We report the synthesis of a series of ruthenium complexes supported by the phosphine olefin ligand tropPPh2 (trop=5-H-dibenzo-[a,d]cyclohepten-5-yl) in the oxidation states 0, +I, and +II, formed via successive one-electron oxidization steps from Ru(0) (tropPPh2 )2 . The bidentate character of the tropPPh2 ligand and its steric hindrance force the complexes to adopt uncommon geometries, which were investigated by X-ray diffraction analysis. EPR data of the mononuclear Ru(I) complex reveal couplings of the unpaired spin with the ruthenium and two phosphorus nuclei, as well as the olefinic protons which show that the spin is mainly localized on the Ru(I) center.

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 10 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 10 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 5 50%
Professor > Associate Professor 2 20%
Student > Master 2 20%
Researcher 1 10%
Readers by discipline Count As %
Chemistry 8 80%
Computer Science 1 10%
Unknown 1 10%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 2. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 29 August 2016.
All research outputs
#15,168,964
of 25,373,627 outputs
Outputs from Angewandte Chemie. International Edition
#33,311
of 49,982 outputs
Outputs of similar age
#194,949
of 351,391 outputs
Outputs of similar age from Angewandte Chemie. International Edition
#372
of 758 outputs
Altmetric has tracked 25,373,627 research outputs across all sources so far. This one is in the 38th percentile – i.e., 38% of other outputs scored the same or lower than it.
So far Altmetric has tracked 49,982 research outputs from this source. They typically receive more attention than average, with a mean Attention Score of 7.8. This one is in the 32nd percentile – i.e., 32% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 351,391 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 42nd percentile – i.e., 42% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 758 others from the same source and published within six weeks on either side of this one. This one is in the 48th percentile – i.e., 48% of its contemporaries scored the same or lower than it.