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Successive Resonances for Ion Ejection at Arbitrary Frequencies in an Ion Trap

Overview of attention for article published in Journal of the American Society for Mass Spectrometry, September 2016
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Title
Successive Resonances for Ion Ejection at Arbitrary Frequencies in an Ion Trap
Published in
Journal of the American Society for Mass Spectrometry, September 2016
DOI 10.1007/s13361-016-1473-2
Pubmed ID
Authors

Dalton T. Snyder, R. Graham Cooks

Abstract

The use of successive resonances for ion ejection is demonstrated here as a method of scanning quadrupole ion traps with improvement in both resolution and sensitivity compared with single frequency resonance ejection. The conventional single frequency resonance ejection waveform is replaced with a dual-frequency waveform. The two included frequencies are spaced very closely and their relative amplitudes are adjusted so that the first frequency that ions encounter excites them to higher amplitudes where space charge effects are less prominent, thereby giving faster and more efficient ejection when the ions come into resonance with the second frequency. The method is applicable at any arbitrary frequency, unlike double and triple resonance methods. However, like double and triple resonance ejection, ejection using successive resonances requires the rf and AC waveforms to be phase-locked in order to retain mass accuracy and mass precision. The improved performance is seen in mass spectra acquired by rf amplitude scans (resonance ejection) as well as by secular frequency scans. Graphical Abstract ᅟ.

X Demographics

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The data shown below were collected from the profiles of 4 X users who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 13 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 13 100%

Demographic breakdown

Readers by professional status Count As %
Researcher 6 46%
Student > Ph. D. Student 3 23%
Student > Bachelor 1 8%
Student > Doctoral Student 1 8%
Unknown 2 15%
Readers by discipline Count As %
Chemistry 7 54%
Physics and Astronomy 2 15%
Environmental Science 1 8%
Unknown 3 23%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 2. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 05 November 2016.
All research outputs
#15,740,207
of 25,374,917 outputs
Outputs from Journal of the American Society for Mass Spectrometry
#2,364
of 3,834 outputs
Outputs of similar age
#200,004
of 344,900 outputs
Outputs of similar age from Journal of the American Society for Mass Spectrometry
#25
of 55 outputs
Altmetric has tracked 25,374,917 research outputs across all sources so far. This one is in the 37th percentile – i.e., 37% of other outputs scored the same or lower than it.
So far Altmetric has tracked 3,834 research outputs from this source. They receive a mean Attention Score of 3.8. This one is in the 36th percentile – i.e., 36% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 344,900 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 40th percentile – i.e., 40% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 55 others from the same source and published within six weeks on either side of this one. This one has gotten more attention than average, scoring higher than 52% of its contemporaries.