Title |
23Na and 27Al NMR Study of Structure and Dynamics in Mordenite
|
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Published in |
Applied Magnetic Resonance, November 2016
|
DOI | 10.1007/s00723-016-0847-8 |
Pubmed ID | |
Authors |
N. A. Sergeev, M. Paczwa, M. Olszewski, A. M. Panich |
Abstract |
Temperature dependencies of (27)Al and (23)Na nuclear magnetic resonance spectra and spin-lattice relaxations in mordenite have been studied in static and magic angle spinning regimes. Our data show that the spin-lattice relaxations of the (23)Na and (27)Al nuclei are mainly governed by interaction of nuclear quadrupole moments with electric field gradients of the crystal, modulated by translational motion of water molecules in the mordenite channels. At temperatures below 200 K, the dipolar interaction of nuclear spins with paramagnetic impurities becomes an important relaxation mechanism of the (23)Na and (27)Al nuclei. |
Mendeley readers
The data shown below were compiled from readership statistics for 11 Mendeley readers of this research output. Click here to see the associated Mendeley record.
Geographical breakdown
Country | Count | As % |
---|---|---|
Unknown | 11 | 100% |
Demographic breakdown
Readers by professional status | Count | As % |
---|---|---|
Student > Ph. D. Student | 3 | 27% |
Researcher | 3 | 27% |
Professor | 2 | 18% |
Professor > Associate Professor | 1 | 9% |
Unknown | 2 | 18% |
Readers by discipline | Count | As % |
---|---|---|
Materials Science | 3 | 27% |
Chemistry | 3 | 27% |
Psychology | 1 | 9% |
Linguistics | 1 | 9% |
Physics and Astronomy | 1 | 9% |
Other | 0 | 0% |
Unknown | 2 | 18% |