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Acetic Acid Ketonization over Fe3O4/SiO2 for Pyrolysis Bio‐Oil Upgrading

Overview of attention for article published in ChemCatChem, January 2017
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Title
Acetic Acid Ketonization over Fe3O4/SiO2 for Pyrolysis Bio‐Oil Upgrading
Published in
ChemCatChem, January 2017
DOI 10.1002/cctc.201601269
Pubmed ID
Authors

James A. Bennett, Christopher M. A. Parlett, Mark A. Isaacs, Lee J. Durndell, Luca Olivi, Adam F. Lee, Karen Wilson

Abstract

A family of silica-supported, magnetite nanoparticle catalysts was synthesised and investigated for continuous-flow acetic acid ketonisation as a model pyrolysis bio-oil upgrading reaction. The physico-chemical properties of Fe3O4/SiO2 catalysts were characterised by using high-resolution transmission electron microscopy, X-ray absorption spectroscopy, X-ray photo-electron spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy, thermogravimetric analysis and porosimetry. The acid site densities were inversely proportional to the Fe3O4 particle size, although the acid strength and Lewis character were size-invariant, and correlated with the specific activity for the vapour-phase acetic ketonisation to acetone. A constant activation energy (∼110 kJ mol(-1)), turnover frequency (∼13 h(-1)) and selectivity to acetone of 60 % were observed for ketonisation across the catalyst series, which implies that Fe3O4 is the principal active component of Red Mud waste.

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 55 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
United Kingdom 1 2%
Unknown 54 98%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 9 16%
Researcher 9 16%
Student > Master 4 7%
Student > Doctoral Student 4 7%
Professor 4 7%
Other 13 24%
Unknown 12 22%
Readers by discipline Count As %
Chemistry 17 31%
Chemical Engineering 11 20%
Engineering 4 7%
Agricultural and Biological Sciences 1 2%
Unspecified 1 2%
Other 2 4%
Unknown 19 35%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 23 July 2018.
All research outputs
#18,518,987
of 22,940,083 outputs
Outputs from ChemCatChem
#3,058
of 5,577 outputs
Outputs of similar age
#309,207
of 418,282 outputs
Outputs of similar age from ChemCatChem
#68
of 148 outputs
Altmetric has tracked 22,940,083 research outputs across all sources so far. This one is in the 11th percentile – i.e., 11% of other outputs scored the same or lower than it.
So far Altmetric has tracked 5,577 research outputs from this source. They receive a mean Attention Score of 2.0. This one is in the 35th percentile – i.e., 35% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 418,282 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 15th percentile – i.e., 15% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 148 others from the same source and published within six weeks on either side of this one. This one has gotten more attention than average, scoring higher than 50% of its contemporaries.