Title |
Hierarchical Porous Polymer Scaffolds from Block Copolymers
|
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Published in |
Science, August 2013
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DOI | 10.1126/science.1238159 |
Pubmed ID | |
Authors |
Hiroaki Sai, Kwan Wee Tan, Kahyun Hur, Emily Asenath-Smith, Robert Hovden, Yi Jiang, Mark Riccio, David A. Muller, Veit Elser, Lara A. Estroff, Sol M. Gruner, Ulrich Wiesner |
Abstract |
Hierarchical porous polymer materials are of increasing importance because of their potential application in catalysis, separation technology, or bioengineering. Examples for their synthesis exist, but there is a need for a facile yet versatile conceptual approach to such hierarchical scaffolds and quantitative characterization of their nonperiodic pore systems. Here, we introduce a synthesis method combining well-established concepts of macroscale spinodal decomposition and nanoscale block copolymer self-assembly with porosity formation on both length scales via rinsing with protic solvents. We used scanning electron microscopy, small-angle x-ray scattering, transmission electron tomography, and nanoscale x-ray computed tomography for quantitative pore-structure characterization. The method was demonstrated for AB- and ABC-type block copolymers, and resulting materials were used as scaffolds for calcite crystal growth. |
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Geographical breakdown
Country | Count | As % |
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United States | 1 | 50% |
Japan | 1 | 50% |
Demographic breakdown
Type | Count | As % |
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Members of the public | 2 | 100% |
Mendeley readers
Geographical breakdown
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Germany | 3 | <1% |
Netherlands | 2 | <1% |
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Canada | 1 | <1% |
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Researcher | 64 | 20% |
Student > Master | 30 | 9% |
Professor | 19 | 6% |
Student > Doctoral Student | 17 | 5% |
Other | 36 | 11% |
Unknown | 48 | 15% |
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Materials Science | 65 | 20% |
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Physics and Astronomy | 23 | 7% |
Chemical Engineering | 19 | 6% |
Other | 16 | 5% |
Unknown | 71 | 22% |