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A field deployable method for a rapid screening analysis of inorganic arsenic in seaweed

Overview of attention for article published in Microchimica Acta, March 2017
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Title
A field deployable method for a rapid screening analysis of inorganic arsenic in seaweed
Published in
Microchimica Acta, March 2017
DOI 10.1007/s00604-017-2151-1
Pubmed ID
Authors

Edi Bralatei, Karolina Nekrosiute, Jenny Ronan, Andrea Raab, Evin McGovern, Dagmar B. Stengel, Eva M. Krupp, Joerg Feldmann

Abstract

Inorganic arsenic (iAs) in 13 store-bought edible seaweed samples and 34 dried kelp (Laminaria digitata) samples was determined by a newly developed, field-deployable method (FDM) with the aid of a field test kit for arsenic in water. Results from the FDM were compared to results from speciation analysis achieved by using high performance liquid chromatography coupled to inductively coupled plasma mass spectrometry (HPLC-ICP-MS). The FDM consisted of a simple extraction method using diluted HNO3 to quantitatively extract iAs without decomposing the organoarsenicals to iAs followed by the selective volatilisation of iAs as arsine (AsH3) and subsequent chemo-trapping on a filter paper soaked in mercury bromide (HgBr2) solution. Method optimization with a sub-set of samples showed 80-94% iAs recovery with the FDM with no matrix effect from organo-arsenic species in the form of dimethylarsinic acid (DMA) on the iAs concentration. The method displayed good reproducibility with an average error of ±19% and validation by HPLC-ICP-MS showed that the results from the FDM were comparable (slope = 1.03, R(2) = 0.70) to those from speciation analysis with no bias. The FDM can be conducted within an hour and the observed limit of quantification was around 0.05 mg kg(-1) (dry weight). This method is well suited for on-site monitoring of iAs in seaweed before it is harvested and can thus be recommended for use as a screening method for iAs in seaweed. Graphical abstractScreening seaweed for their inorganic arsenic concentration within one hour without bias has been made possible in the field by using a field deployable arsenic kit. Its accuracy and precision was compared to HPLC-ICPMS.

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 54 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 54 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 8 15%
Researcher 5 9%
Student > Bachelor 4 7%
Student > Doctoral Student 3 6%
Professor 2 4%
Other 9 17%
Unknown 23 43%
Readers by discipline Count As %
Chemistry 9 17%
Agricultural and Biological Sciences 7 13%
Computer Science 2 4%
Environmental Science 2 4%
Biochemistry, Genetics and Molecular Biology 1 2%
Other 6 11%
Unknown 27 50%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 31 March 2017.
All research outputs
#15,451,618
of 22,961,203 outputs
Outputs from Microchimica Acta
#669
of 1,396 outputs
Outputs of similar age
#210,749
of 334,647 outputs
Outputs of similar age from Microchimica Acta
#14
of 19 outputs
Altmetric has tracked 22,961,203 research outputs across all sources so far. This one is in the 22nd percentile – i.e., 22% of other outputs scored the same or lower than it.
So far Altmetric has tracked 1,396 research outputs from this source. They receive a mean Attention Score of 2.4. This one is in the 42nd percentile – i.e., 42% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 334,647 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 28th percentile – i.e., 28% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 19 others from the same source and published within six weeks on either side of this one. This one is in the 10th percentile – i.e., 10% of its contemporaries scored the same or lower than it.