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Nanoparticles of Well‐Defined 4‐Arm Stars made using Nanoreactors in Water

Overview of attention for article published in Macromolecular Rapid Communications, November 2013
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Title
Nanoparticles of Well‐Defined 4‐Arm Stars made using Nanoreactors in Water
Published in
Macromolecular Rapid Communications, November 2013
DOI 10.1002/marc.201300665
Pubmed ID
Authors

Khaled O Sebakhy, Mikhail Gavrilov, David Valade, Zhongfan Jia, Michael J Monteiro

Abstract

In this work, the use of a nanoreactor is demonstrated to rapidly prepare monodisperse polymer nanoparticles in water-based dispersion consisting of 4-arm star polymer via the R-group RAFT approach. It is shown that by heating a nanoparticle assembler above its lower critical solution temperature (LCST), stabilized nanoparticles are formed that act as a template for the 4-arm star RAFT-mediated polymerization of styrene. Monodisperse nanoparticles of size (between 40 and 90 nm) containing monodisperse polymer of desired molecular weight (30-95 k) are obtained with little star-star coupling due to compartmentalization. The nanoreactor technique allows independent control over the size and molecular weight with a 4-arm star topology.

Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 12 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 12 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 5 42%
Student > Master 2 17%
Lecturer 1 8%
Student > Doctoral Student 1 8%
Lecturer > Senior Lecturer 1 8%
Other 0 0%
Unknown 2 17%
Readers by discipline Count As %
Chemistry 7 58%
Chemical Engineering 1 8%
Agricultural and Biological Sciences 1 8%
Business, Management and Accounting 1 8%
Unknown 2 17%