Title |
Solvent exchange in a metal–organic framework single crystal monitored by dynamic in situ X‐ray diffraction
|
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Published in |
ACTA CRYSTALLOGRAPHICA SECTION B, July 2017
|
DOI | 10.1107/s2052520617008447 |
Pubmed ID | |
Authors |
Jordan M. Cox, Ian M. Walton, Gage Bateman, Cassidy A. Benson, Travis Mitchell, Eric Sylvester, Yu-Sheng Chen, Jason B. Benedict |
Abstract |
Understanding the processes by which porous solid-state materials adsorb and release guest molecules would represent a significant step towards developing rational design principles for functional porous materials. To elucidate the process of liquid exchange in these materials, dynamic in situ X-ray diffraction techniques have been developed which utilize liquid-phase chemical stimuli. Using these time-resolved diffraction techniques, the ethanol solvation process in a flexible metal-organic framework [Co(AIP)(bpy)0.5(H2O)]·2H2O was examined. The measurements provide important insight into the nature of the chemical transformation in this system including the presence of a previously unreported neat ethanol solvate structure. |
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