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Amine α-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway

Overview of attention for article published in Chemical Science, January 2014
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About this Attention Score

  • In the top 25% of all research outputs scored by Altmetric
  • High Attention Score compared to outputs of the same age (82nd percentile)
  • Good Attention Score compared to outputs of the same age and source (65th percentile)

Mentioned by

news
1 news outlet

Citations

dimensions_citation
157 Dimensions

Readers on

mendeley
192 Mendeley
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Title
Amine α-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway
Published in
Chemical Science, January 2014
DOI 10.1039/c4sc02155j
Pubmed ID
Authors

Christopher K Prier, David W C MacMillan

Abstract

The direct α-heteroarylation of tertiary amines has been accomplished via photoredox catalysis to generate valuable benzylic amine pharmacophores. A variety of five-and six-membered chloroheteroarenes are shown to function as viable coupling partners for the α-arylation of a diverse range of cyclic and acyclic amines. Evidence is provided for a homolytic aromatic substitution mechanism, in which a catalyticallygenerated α-amino radical undergoes direct addition to an electrophilic chloroarene.

Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 192 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
United States 3 2%
United Kingdom 1 <1%
Denmark 1 <1%
Belgium 1 <1%
Unknown 186 97%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 46 24%
Researcher 34 18%
Student > Master 27 14%
Student > Doctoral Student 17 9%
Student > Bachelor 13 7%
Other 26 14%
Unknown 29 15%
Readers by discipline Count As %
Chemistry 144 75%
Social Sciences 3 2%
Pharmacology, Toxicology and Pharmaceutical Science 2 1%
Engineering 2 1%
Materials Science 2 1%
Other 5 3%
Unknown 34 18%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 7. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 14 August 2014.
All research outputs
#4,165,692
of 22,760,687 outputs
Outputs from Chemical Science
#2,431
of 7,784 outputs
Outputs of similar age
#49,928
of 305,286 outputs
Outputs of similar age from Chemical Science
#91
of 295 outputs
Altmetric has tracked 22,760,687 research outputs across all sources so far. Compared to these this one has done well and is in the 80th percentile: it's in the top 25% of all research outputs ever tracked by Altmetric.
So far Altmetric has tracked 7,784 research outputs from this source. They typically receive more attention than average, with a mean Attention Score of 7.6. This one has gotten more attention than average, scoring higher than 67% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 305,286 tracked outputs that were published within six weeks on either side of this one in any source. This one has done well, scoring higher than 82% of its contemporaries.
We're also able to compare this research output to 295 others from the same source and published within six weeks on either side of this one. This one has gotten more attention than average, scoring higher than 65% of its contemporaries.