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Synthesis of Arylamines via Aminium Radicals

Overview of attention for article published in Angewandte Chemie. International Edition, October 2017
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About this Attention Score

  • In the top 5% of all research outputs scored by Altmetric
  • High Attention Score compared to outputs of the same age (92nd percentile)
  • High Attention Score compared to outputs of the same age and source (94th percentile)

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2 blogs
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1 patent

Citations

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129 Mendeley
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Title
Synthesis of Arylamines via Aminium Radicals
Published in
Angewandte Chemie. International Edition, October 2017
DOI 10.1002/anie.201708693
Pubmed ID
Authors

Thomas D. Svejstrup, Alessandro Ruffoni, Fabio Juliá, Valentin M. Aubert, Daniele Leonori

Abstract

Arylamines constitute the core structure of many therapeutic agents, agrochemicals and organic materials. The development of methodologies for the efficient and selective construction of these structural motifs from simple building blocks is desirable but still challenging. Here, we demonstrate that protonated electron poor O-aryl hydroxylamines lead, in the presence of Ru(bpy)3Cl2, to the formation of aminium radicals. These highly electrophilic species undergo polarized radical addition to aromatics in high yield and selectivity. We have successfully applied this methodology to the late-stage modification of chiral catalyst templates, therapeutic agents and natural products.

X Demographics

X Demographics

The data shown below were collected from the profiles of 25 X users who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 129 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 129 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 49 38%
Researcher 13 10%
Student > Master 10 8%
Student > Doctoral Student 8 6%
Student > Bachelor 6 5%
Other 16 12%
Unknown 27 21%
Readers by discipline Count As %
Chemistry 91 71%
Unspecified 1 <1%
Nursing and Health Professions 1 <1%
Social Sciences 1 <1%
Computer Science 1 <1%
Other 2 2%
Unknown 32 25%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 34. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 05 October 2023.
All research outputs
#1,184,945
of 25,621,213 outputs
Outputs from Angewandte Chemie. International Edition
#1,630
of 50,442 outputs
Outputs of similar age
#24,206
of 339,006 outputs
Outputs of similar age from Angewandte Chemie. International Edition
#43
of 791 outputs
Altmetric has tracked 25,621,213 research outputs across all sources so far. Compared to these this one has done particularly well and is in the 95th percentile: it's in the top 5% of all research outputs ever tracked by Altmetric.
So far Altmetric has tracked 50,442 research outputs from this source. They typically receive more attention than average, with a mean Attention Score of 7.8. This one has done particularly well, scoring higher than 96% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 339,006 tracked outputs that were published within six weeks on either side of this one in any source. This one has done particularly well, scoring higher than 92% of its contemporaries.
We're also able to compare this research output to 791 others from the same source and published within six weeks on either side of this one. This one has done particularly well, scoring higher than 94% of its contemporaries.