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On the Non‐Metallicity of 2.2 nm Au246(SR)80 Nanoclusters

Overview of attention for article published in Angewandte Chemie. International Edition, November 2017
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Title
On the Non‐Metallicity of 2.2 nm Au246(SR)80 Nanoclusters
Published in
Angewandte Chemie. International Edition, November 2017
DOI 10.1002/anie.201709095
Pubmed ID
Authors

Meng Zhou, Chenjie Zeng, Yongbo Song, Jonathan W. Padelford, Gangli Wang, Matthew Y. Sfeir, Tatsuya Higaki, Rongchao Jin

Abstract

The transition from molecular to plasmonic behaviour in metal nanoparticles with increasing size remains a central question in nanoscience. We report that the giant 246-gold-atom nanocluster (2.2 nm in gold core diameter) protected by 80 thiolate ligands is surprisingly non-metallic based on UV-vis and femtosecond transient absorption spectroscopy as well as electrochemical measurements. Specifically, the Au246 nanocluster exhibits multiple excitonic peaks in transient absorption spectra and electron dynamics independent of the pump power, which are in contrast to the behaviour of metallic gold nanoparticles. Moreover, a prominent oscillatory feature with frequency of 0.5 THz can be observed in almost all the probe wavelengths. The phase and amplitude analysis of the oscillation suggests that it arises from the wavepacket motion on the ground state potential energy surface, which also indicates the presence of a small band-gap and thus non-metallic or molecular-like behaviour.

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 36 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 36 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 12 33%
Student > Bachelor 5 14%
Student > Doctoral Student 3 8%
Student > Master 3 8%
Researcher 3 8%
Other 4 11%
Unknown 6 17%
Readers by discipline Count As %
Chemistry 17 47%
Physics and Astronomy 5 14%
Materials Science 3 8%
Pharmacology, Toxicology and Pharmaceutical Science 1 3%
Agricultural and Biological Sciences 1 3%
Other 0 0%
Unknown 9 25%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 3. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 23 November 2017.
All research outputs
#14,605,790
of 25,382,440 outputs
Outputs from Angewandte Chemie. International Edition
#31,622
of 50,006 outputs
Outputs of similar age
#218,200
of 445,683 outputs
Outputs of similar age from Angewandte Chemie. International Edition
#485
of 752 outputs
Altmetric has tracked 25,382,440 research outputs across all sources so far. This one is in the 41st percentile – i.e., 41% of other outputs scored the same or lower than it.
So far Altmetric has tracked 50,006 research outputs from this source. They typically receive more attention than average, with a mean Attention Score of 7.8. This one is in the 35th percentile – i.e., 35% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 445,683 tracked outputs that were published within six weeks on either side of this one in any source. This one has gotten more attention than average, scoring higher than 50% of its contemporaries.
We're also able to compare this research output to 752 others from the same source and published within six weeks on either side of this one. This one is in the 34th percentile – i.e., 34% of its contemporaries scored the same or lower than it.