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Attention Score in Context
Title |
Synthesis of spirocyclic orthoesters by ‘anomalous’ rhodium( ii )-catalysed intramolecular C–H insertions
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Published in |
Organic and Biomolecular Chemistry, January 2018
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DOI | 10.1039/c7ob02123b |
Pubmed ID | |
Authors |
Fanny J. Lombard, Romain J. Lepage, Brett D. Schwartz, Ryne C. Johnston, Peter C. Healy, Elizabeth H. Krenske, Mark J. Coster |
Abstract |
A tetrahydropyranyl acetal bearing a proximal phenyl diazoketone substituent underwent Rh(ii)-catalysed C-H insertion via an 'anomalous' C-O bond-forming, rather than C-C bond-forming, transformation, giving spirocyclic orthoesters. Density functional theory calculations with M06 show that the formation of these anomalous products involves hydride transfer to the rhodium carbene, giving an intermediate zwitterion which undergoes C-O bond formation in preference to C-C bond formation. |
X Demographics
The data shown below were collected from the profiles of 4 X users who shared this research output. Click here to find out more about how the information was compiled.
Geographical breakdown
Country | Count | As % |
---|---|---|
United Kingdom | 1 | 25% |
Australia | 1 | 25% |
Unknown | 2 | 50% |
Demographic breakdown
Type | Count | As % |
---|---|---|
Members of the public | 2 | 50% |
Scientists | 2 | 50% |
Mendeley readers
The data shown below were compiled from readership statistics for 6 Mendeley readers of this research output. Click here to see the associated Mendeley record.
Geographical breakdown
Country | Count | As % |
---|---|---|
Unknown | 6 | 100% |
Demographic breakdown
Readers by professional status | Count | As % |
---|---|---|
Researcher | 3 | 50% |
Professor | 1 | 17% |
Student > Bachelor | 1 | 17% |
Professor > Associate Professor | 1 | 17% |
Readers by discipline | Count | As % |
---|---|---|
Chemistry | 4 | 67% |
Unknown | 2 | 33% |
Attention Score in Context
This research output has an Altmetric Attention Score of 10. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 21 May 2019.
All research outputs
#3,597,191
of 25,756,911 outputs
Outputs from Organic and Biomolecular Chemistry
#325
of 6,872 outputs
Outputs of similar age
#73,208
of 452,073 outputs
Outputs of similar age from Organic and Biomolecular Chemistry
#17
of 351 outputs
Altmetric has tracked 25,756,911 research outputs across all sources so far. Compared to these this one has done well and is in the 86th percentile: it's in the top 25% of all research outputs ever tracked by Altmetric.
So far Altmetric has tracked 6,872 research outputs from this source. They receive a mean Attention Score of 3.7. This one has done particularly well, scoring higher than 94% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 452,073 tracked outputs that were published within six weeks on either side of this one in any source. This one has done well, scoring higher than 83% of its contemporaries.
We're also able to compare this research output to 351 others from the same source and published within six weeks on either side of this one. This one has done particularly well, scoring higher than 94% of its contemporaries.