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Amphiphile Micelle Structures in the Protic Ionic Liquid Ethylammonium Nitrate and Water

Overview of attention for article published in Journal of Physical Chemistry B, December 2014
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  • Above-average Attention Score compared to outputs of the same age and source (57th percentile)

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Title
Amphiphile Micelle Structures in the Protic Ionic Liquid Ethylammonium Nitrate and Water
Published in
Journal of Physical Chemistry B, December 2014
DOI 10.1021/jp509557z
Pubmed ID
Authors

Zhengfei Chen, Tamar L. Greaves, Rachel A. Caruso, Calum J. Drummond

Abstract

Micelles formed by amphiphiles in a protic ionic liquid (PIL), ethylammonium nitrate (EAN), were investigated using synchrotron small-angle X-ray scattering and contrasted with those that formed in water. The amphiphiles studied were cationic hexadecyltrimethylammonium chloride (CTAC) and hexadecylpyridinium bromide (HDPB) and nonionic poly(oxyethylene) (10) oleyl ether (Brij 97) and Pluronic ethylene oxide-propylene oxide-ethylene oxide block copolymer (P123). The scattering patterns were analyzed using spherical, core-shell, and cylindrical scattering models. The apparent micelle shape and size of the surfactants and the block copolymer in the PIL have been reported. At low amphiphile concentrations (<10 wt %) spherical micelles were preferentially formed for all the amphiphiles in EAN. The micelles formed by the two cationic amphiphiles in EAN and water were similar, though different scattering models were required predominantly due to the ionic nature of EAN. The two nonionic amphiphiles formed micelles with similar core radii in water and in EAN. However, the micelle shells composed of ethylene oxide groups fitted to a significantly thicker layer in water compared to EAN. At high concentrations (>10 wt %) in EAN and water, there was a preference for cylindrical micelles for CTAC, HDPB, and Brij 97; however, the P123 micelles remained spherical.

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 27 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 27 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 13 48%
Researcher 3 11%
Student > Master 3 11%
Student > Doctoral Student 2 7%
Lecturer > Senior Lecturer 1 4%
Other 1 4%
Unknown 4 15%
Readers by discipline Count As %
Chemistry 17 63%
Chemical Engineering 2 7%
Materials Science 2 7%
Physics and Astronomy 1 4%
Biochemistry, Genetics and Molecular Biology 1 4%
Other 1 4%
Unknown 3 11%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 08 January 2015.
All research outputs
#17,286,645
of 25,374,917 outputs
Outputs from Journal of Physical Chemistry B
#8,927
of 14,906 outputs
Outputs of similar age
#220,422
of 359,929 outputs
Outputs of similar age from Journal of Physical Chemistry B
#60
of 191 outputs
Altmetric has tracked 25,374,917 research outputs across all sources so far. This one is in the 21st percentile – i.e., 21% of other outputs scored the same or lower than it.
So far Altmetric has tracked 14,906 research outputs from this source. They receive a mean Attention Score of 2.9. This one is in the 34th percentile – i.e., 34% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 359,929 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 29th percentile – i.e., 29% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 191 others from the same source and published within six weeks on either side of this one. This one has gotten more attention than average, scoring higher than 57% of its contemporaries.