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A Non‐Heme Iron Photocatalyst for Light‐Driven Aerobic Oxidation of Methanol

Overview of attention for article published in Angewandte Chemie. International Edition, February 2018
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Title
A Non‐Heme Iron Photocatalyst for Light‐Driven Aerobic Oxidation of Methanol
Published in
Angewandte Chemie. International Edition, February 2018
DOI 10.1002/anie.201712678
Pubmed ID
Authors

Juan Chen, Stepan Stepanovic, Apparao Draksharapu, Maja Gruden, Wesley R. Browne

Abstract

The non-heme (L)FeIII and (L)FeIII-O-FeIII(L) complexes (L = 1,1-di(pyridin-2-yl)-N,N-bis(pyridin-2-ylmethyl)ethan-1-amine) undergoes reduction under irradiation to the FeII state with concomitant oxidation of methanol to methanal, without the need for a secondary photosensitizer. Spectroscopic and Density Functional Theory (DFT) studies support a mechanism in which irradiation results in charge transfer excitation of a FeIII--O-FeIII complex to generate [(L)FeIV=O]2+ (observed transiently during irradiation in acetonitrile), and an equivalent of LFeII. Under aerobic conditions, irradiation accelerates reoxidation from the FeII to FeIII state with O2 closing the cycle of methanol oxidation to methanal.

X Demographics

X Demographics

The data shown below were collected from the profiles of 6 X users who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 38 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 38 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 12 32%
Student > Bachelor 5 13%
Student > Master 4 11%
Professor > Associate Professor 3 8%
Other 3 8%
Other 4 11%
Unknown 7 18%
Readers by discipline Count As %
Chemistry 25 66%
Biochemistry, Genetics and Molecular Biology 2 5%
Computer Science 1 3%
Energy 1 3%
Physics and Astronomy 1 3%
Other 0 0%
Unknown 8 21%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 3. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 21 February 2018.
All research outputs
#14,393,794
of 25,382,440 outputs
Outputs from Angewandte Chemie. International Edition
#30,936
of 50,006 outputs
Outputs of similar age
#167,820
of 344,213 outputs
Outputs of similar age from Angewandte Chemie. International Edition
#420
of 776 outputs
Altmetric has tracked 25,382,440 research outputs across all sources so far. This one is in the 42nd percentile – i.e., 42% of other outputs scored the same or lower than it.
So far Altmetric has tracked 50,006 research outputs from this source. They typically receive more attention than average, with a mean Attention Score of 7.8. This one is in the 37th percentile – i.e., 37% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 344,213 tracked outputs that were published within six weeks on either side of this one in any source. This one has gotten more attention than average, scoring higher than 50% of its contemporaries.
We're also able to compare this research output to 776 others from the same source and published within six weeks on either side of this one. This one is in the 44th percentile – i.e., 44% of its contemporaries scored the same or lower than it.