Title |
Oxygen-deficient photostable Cu 2 O for enhanced visible light photocatalytic activity
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Published in |
Nanoscale, January 2018
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DOI | 10.1039/c7nr08388b |
Pubmed ID | |
Authors |
Mandeep Singh, Deshetti Jampaiah, Ahmad E Kandjani, Ylias M Sabri, Enrico Della Gaspera, Philipp Reineck, Martyna Judd, Julien Langley, Nicholas Cox, Joel van Embden, Edwin L H Mayes, Brant C Gibson, Suresh K Bhargava, Rajesh Ramanathan, Vipul Bansal |
Abstract |
Oxygen vacancies in inorganic semiconductors play an important role in reducing electron-hole recombination, which may have important implications in photocatalysis. Cuprous oxide (Cu2O), a visible light active p-type semiconductor, is a promising photocatalyst. However, the synthesis of photostable Cu2O enriched with oxygen defects remains a challenge. We report a simple method for the gram-scale synthesis of highly photostable Cu2O nanoparticles by the hydrolysis of a Cu(i)-triethylamine [Cu(i)-TEA] complex at low temperature. The oxygen vacancies in these Cu2O nanoparticles led to a significant increase in the lifetimes of photogenerated charge carriers upon excitation with visible light. This, in combination with a suitable energy band structure, allowed Cu2O nanoparticles to exhibit outstanding photoactivity in visible light through the generation of electron-mediated hydroxyl (OH˙) radicals. This study highlights the significance of oxygen defects in enhancing the photocatalytic performance of promising semiconductor photocatalysts. |
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