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The advantages of covalently attaching organometallic catalysts to a carbon black support: recyclable Rh( i ) complexes that deliver enhanced conversion and product selectivity

Overview of attention for article published in Dalton Transactions: An International Journal of Inorganic Chemistry, January 2015
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  • Above-average Attention Score compared to outputs of the same age and source (59th percentile)

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Title
The advantages of covalently attaching organometallic catalysts to a carbon black support: recyclable Rh( i ) complexes that deliver enhanced conversion and product selectivity
Published in
Dalton Transactions: An International Journal of Inorganic Chemistry, January 2015
DOI 10.1039/c5dt00409h
Pubmed ID
Authors

Andrey A. Tregubov, D. Barney Walker, Khuong Q. Vuong, J. Justin Gooding, Barbara A. Messerle

Abstract

Pure carbon black (CB) was covalently attached to a bidentate nitrogen coordination motif with a carbon-carbon bond by spontaneous reaction with an in situ generated ligand precursor. The functionalized support was treated with [Rh(CO)2(μ-Cl)]2 to form a heterogeneous carbon-based support covalently linked to a well defined Rh(i) coordination complex. The hybrid material was characterized using X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), Infrared (IR) spectroscopy and inductively coupled plasma mass spectrometry (ICP-MS). The CB-supported Rh(i) catalyst was active in both hydroamination and dihydroalkoxylation reactions achieving turnover numbers approaching 1000 and was readily recycled. The selectivity of an intramolecular dihydroalkoxylation reaction was significantly improved by covalently anchoring the catalyst to the CB surface.

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X Demographics

The data shown below were collected from the profile of 1 X user who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 26 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Canada 1 4%
Unknown 25 96%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 9 35%
Researcher 6 23%
Professor 2 8%
Student > Master 2 8%
Lecturer 1 4%
Other 1 4%
Unknown 5 19%
Readers by discipline Count As %
Chemistry 15 58%
Materials Science 2 8%
Energy 1 4%
Business, Management and Accounting 1 4%
Economics, Econometrics and Finance 1 4%
Other 1 4%
Unknown 5 19%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 11 May 2015.
All research outputs
#20,970,494
of 25,756,911 outputs
Outputs from Dalton Transactions: An International Journal of Inorganic Chemistry
#11,294
of 21,221 outputs
Outputs of similar age
#268,963
of 361,654 outputs
Outputs of similar age from Dalton Transactions: An International Journal of Inorganic Chemistry
#817
of 2,236 outputs
Altmetric has tracked 25,756,911 research outputs across all sources so far. This one is in the 10th percentile – i.e., 10% of other outputs scored the same or lower than it.
So far Altmetric has tracked 21,221 research outputs from this source. They receive a mean Attention Score of 1.8. This one is in the 40th percentile – i.e., 40% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 361,654 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 14th percentile – i.e., 14% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 2,236 others from the same source and published within six weeks on either side of this one. This one has gotten more attention than average, scoring higher than 59% of its contemporaries.