Title |
Accurate lineshape spectroscopy and the Boltzmann constant
|
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Published in |
Nature Communications, October 2015
|
DOI | 10.1038/ncomms9345 |
Pubmed ID | |
Authors |
G.-W. Truong, J. D. Anstie, E. F. May, T. M. Stace, A. N. Luiten |
Abstract |
Spectroscopy has an illustrious history delivering serendipitous discoveries and providing a stringent testbed for new physical predictions, including applications from trace materials detection, to understanding the atmospheres of stars and planets, and even constraining cosmological models. Reaching fundamental-noise limits permits optimal extraction of spectroscopic information from an absorption measurement. Here, we demonstrate a quantum-limited spectrometer that delivers high-precision measurements of the absorption lineshape. These measurements yield a very accurate measurement of the excited-state (6P1/2) hyperfine splitting in Cs, and reveals a breakdown in the well-known Voigt spectral profile. We develop a theoretical model that accounts for this breakdown, explaining the observations to within the shot-noise limit. Our model enables us to infer the thermal velocity dispersion of the Cs vapour with an uncertainty of 35 p.p.m. within an hour. This allows us to determine a value for Boltzmann's constant with a precision of 6 p.p.m., and an uncertainty of 71 p.p.m. |
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Unknown | 49 | 92% |
Demographic breakdown
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Student > Ph. D. Student | 10 | 19% |
Professor | 6 | 11% |
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Other | 7 | 13% |
Unknown | 7 | 13% |
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Other | 2 | 4% |
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