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A New Structural Family of Gas‐Sorbing Coordination Polymers Derived from Phenolic Carboxylic Acids

Overview of attention for article published in Chemistry - A European Journal, November 2015
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About this Attention Score

  • Good Attention Score compared to outputs of the same age (71st percentile)
  • Good Attention Score compared to outputs of the same age and source (79th percentile)

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2 X users
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1 patent
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1 Facebook page

Citations

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26 Mendeley
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Title
A New Structural Family of Gas‐Sorbing Coordination Polymers Derived from Phenolic Carboxylic Acids
Published in
Chemistry - A European Journal, November 2015
DOI 10.1002/chem.201503252
Pubmed ID
Authors

Keith F. White, Brendan F. Abrahams, Ravichandar Babarao, A. David Dharma, Timothy A. Hudson, Helen E. Maynard‐Casely, Richard Robson

Abstract

The structure of Li(inox)⋅2/3 DMF (inox(-) =the N-oxide of the isonicotinate anion) consists of a 3D framework with solvent-filled, square cross-section channels of approximate dimensions 5.5×5.5 Å. Unfortunately, the Li(inox) framework is unstable upon removal of DMF from the channels. When the structurally related 4-hydroxybenzoic acid (H2 hba) was used in place of Hinox, and Zn(2+) in place of the Li(+) , a structurally similar but more robust network, Zn(hba), was obtained; the isostructural compound, Co(hba), may also be prepared. Longer ligands with phenolate and carboxylate functional groups at opposite ends, such as the dianions of 4-coumaric acid (H2 cma) and 4'-hydroxy-4-biphenylcarboxylic acid (H2 hbpc), in combination with Zn(2+) yield Zn(cma) and Zn(hbpc) frameworks, respectively, with the same PtS topology but with larger channels. The coordination polymers remain intact after desolvation and exhibit microporosity, showing the ability to sorb significant quantities of CO2 , CH4 , and H2 .

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 26 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 26 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 6 23%
Researcher 6 23%
Student > Master 3 12%
Other 2 8%
Professor 1 4%
Other 2 8%
Unknown 6 23%
Readers by discipline Count As %
Chemistry 13 50%
Biochemistry, Genetics and Molecular Biology 1 4%
Materials Science 1 4%
Medicine and Dentistry 1 4%
Unknown 10 38%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 5. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 17 January 2019.
All research outputs
#6,928,704
of 24,602,766 outputs
Outputs from Chemistry - A European Journal
#5,817
of 22,950 outputs
Outputs of similar age
#82,457
of 290,792 outputs
Outputs of similar age from Chemistry - A European Journal
#83
of 410 outputs
Altmetric has tracked 24,602,766 research outputs across all sources so far. This one has received more attention than most of these and is in the 71st percentile.
So far Altmetric has tracked 22,950 research outputs from this source. They receive a mean Attention Score of 3.9. This one has gotten more attention than average, scoring higher than 74% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 290,792 tracked outputs that were published within six weeks on either side of this one in any source. This one has gotten more attention than average, scoring higher than 71% of its contemporaries.
We're also able to compare this research output to 410 others from the same source and published within six weeks on either side of this one. This one has done well, scoring higher than 79% of its contemporaries.