Title |
Interaction of Graphene Quantum Dots with 4-Acetamido-2,2,6,6-Tetramethylpiperidine-Oxyl Free Radicals: A Spectroscopic and Fluorimetric Study
|
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Published in |
Journal of Fluorescence, November 2015
|
DOI | 10.1007/s10895-015-1712-0 |
Pubmed ID | |
Authors |
Ojodomo J. Achadu, Tebello Nyokong |
Abstract |
We report on the interaction of graphene quantum dots (GQDs) with 4-acetamido-2,2,6,6-tetramethylpiperidine-oxyl (4-acetamido-TEMPO) free radicals. The GQDs were N and S, N doped. The fluorescence quantum yields were higher for the doped GQDs compared to the undoped. The interaction is assessed by spectrofluorimetric, steady state/time resolved fluorescence and electron paramagnetic resonance (EPR) techniques. Fluorescence quenching was observed upon the addition of 4-acetamido-TEMPO to the GQDs. Photo-induced electron transfer (PET) mechanism was suggested as the plausible mechanism involved in the fluorescence quenching in which 4-acetamido-TEMPO acted as the electron acceptor. |
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