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Uncommon Pyrazoyl-Carboxyl Bifunctional Ligand-Based Microporous Lanthanide Systems: Sorption and Luminescent Sensing Properties

Overview of attention for article published in Inorganic Chemistry, March 2016
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Title
Uncommon Pyrazoyl-Carboxyl Bifunctional Ligand-Based Microporous Lanthanide Systems: Sorption and Luminescent Sensing Properties
Published in
Inorganic Chemistry, March 2016
DOI 10.1021/acs.inorgchem.6b00217
Pubmed ID
Authors

Gao-Peng Li, Ge Liu, Yong-Zhi Li, Lei Hou, Yao-Yu Wang, Zhonghua Zhu

Abstract

Seven new isostructural lanthanide metal-organic frameworks (Ln-MOFs), [Ln(Hpzbc)2(NO3)]·H2O (1-Ln, Ln = Nd(3+), Sm(3+), Eu(3+), Gd(3+), Tb(3+), Er(3+), and Yb(3+) ions, H2pzbc = 3-(1H-pyrazol-3-yl) benzoic acid), with one-dimensional (1D) channels decorated by nitrate anions and pyrazoyl groups have been constructed. 1-Ln, as revealed by structural analysis, represent uncommon microporous 3D Ln-pyrazoyl-carboxyl systems using pyrazoyl-carboxyl bifunctional ligands as bridges. The luminescent investigations show that 1-Eu is an excellent MOF-based fluorescent probe, with high sensitivity, selectivity, and simple regeneration, for environmentally relevant Fe(3+) and Cr2O7(2-) ions. 1-Eu also presents highly selective capture for CO2 over N2 and CH4 due to the multiple binding sites for CO2 molecules, which were supported by Grand Canonical Monte Carlo (GCMC) simulations.

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 50 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Brazil 1 2%
Unknown 49 98%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 7 14%
Researcher 5 10%
Professor 5 10%
Student > Master 4 8%
Other 4 8%
Other 9 18%
Unknown 16 32%
Readers by discipline Count As %
Chemistry 28 56%
Psychology 1 2%
Biochemistry, Genetics and Molecular Biology 1 2%
Medicine and Dentistry 1 2%
Physics and Astronomy 1 2%
Other 0 0%
Unknown 18 36%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 29 March 2016.
All research outputs
#17,795,140
of 22,858,915 outputs
Outputs from Inorganic Chemistry
#17,014
of 21,691 outputs
Outputs of similar age
#206,342
of 300,926 outputs
Outputs of similar age from Inorganic Chemistry
#163
of 373 outputs
Altmetric has tracked 22,858,915 research outputs across all sources so far. This one is in the 19th percentile – i.e., 19% of other outputs scored the same or lower than it.
So far Altmetric has tracked 21,691 research outputs from this source. They receive a mean Attention Score of 2.8. This one is in the 15th percentile – i.e., 15% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 300,926 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 26th percentile – i.e., 26% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 373 others from the same source and published within six weeks on either side of this one. This one is in the 41st percentile – i.e., 41% of its contemporaries scored the same or lower than it.