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Convergence of the multipole expansions of the polarization and dispersion interactions for atoms under confinement

Overview of attention for article published in Journal of Chemical Physics, May 2012
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Title
Convergence of the multipole expansions of the polarization and dispersion interactions for atoms under confinement
Published in
Journal of Chemical Physics, May 2012
DOI 10.1063/1.4705279
Pubmed ID
Authors

Yong-Hui Zhang, Li-Yan Tang, Xian-Zhou Zhang, Jun Jiang, J. Mitroy

Abstract

The multipole expansion of the polarization interaction between a charged particle and an electrically neutral object has long been known to be asymptotic in nature, i.e., the multiple expansion diverges at any finite distance from the atom. However, the multipole expansion of the polarization potential of a confined hydrogen atom is shown to be absolutely convergent at a distance outside the confinement radius, R(0), of the atom. The multipole expansion of the dispersion potential between two confined hydrogen atoms is also shown to be absolutely convergent provided the two atoms satisfy R > 2R(0), where R is the inter-nuclear separation. These results were established analytically using oscillator strength sum rules and verified numerically using a B-spline description of the hydrogen ground state and its excitation spectrum.

Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 14 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
United States 1 7%
Unknown 13 93%

Demographic breakdown

Readers by professional status Count As %
Professor 5 36%
Researcher 3 21%
Professor > Associate Professor 3 21%
Student > Postgraduate 2 14%
Student > Ph. D. Student 1 7%
Other 0 0%
Readers by discipline Count As %
Chemistry 9 64%
Physics and Astronomy 4 29%
Unknown 1 7%