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Influence of Tetraazamacrocyclic Ligands on the Nitric Oxide Reactivity of their Cobalt(II) Complexes

Overview of attention for article published in Journal of the American Chemical Society, June 2012
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Title
Influence of Tetraazamacrocyclic Ligands on the Nitric Oxide Reactivity of their Cobalt(II) Complexes
Published in
Journal of the American Chemical Society, June 2012
DOI 10.1021/ja305011g
Pubmed ID
Authors

Julia Kozhukh, Stephen J. Lippard

Abstract

The reactions of cobalt(II) complexes of tetraazamacrocyclic tropocoronand (TC) ligands with nitric oxide (NO) were investigated. When [Co(TC-5,5)] was allowed to react with NO(g), the {CoNO}(8) mononitrosyl [Co(NO)(TC-5,5)] was isolated and structurally characterized. In contrast, a {Co(NO)(2)}(10) species formed when [Co(TC-6,6)] was exposed to NO(g), and the nitrito [Co(NO(2))(TC-6,6)] complex was structurally and spectroscopically characterized from the reaction mixture. The {Co(NO)(2)}(10) species was assigned as the bis(cobalt dinitrosyl) complex [Co(2)(NO)(4)(TC-6,6)] by spectroscopic comparison with independently synthesized and characterized material. These results provide the first evidence for the influence of tropocoronand ring size on the nitric oxide reactivity of the cobalt(II) complexes.

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 26 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 26 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 6 23%
Student > Doctoral Student 4 15%
Researcher 3 12%
Student > Bachelor 2 8%
Other 2 8%
Other 5 19%
Unknown 4 15%
Readers by discipline Count As %
Chemistry 19 73%
Arts and Humanities 1 4%
Physics and Astronomy 1 4%
Medicine and Dentistry 1 4%
Unknown 4 15%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 28 June 2012.
All research outputs
#15,246,403
of 22,669,724 outputs
Outputs from Journal of the American Chemical Society
#55,304
of 61,765 outputs
Outputs of similar age
#104,813
of 164,434 outputs
Outputs of similar age from Journal of the American Chemical Society
#427
of 565 outputs
Altmetric has tracked 22,669,724 research outputs across all sources so far. This one is in the 22nd percentile – i.e., 22% of other outputs scored the same or lower than it.
So far Altmetric has tracked 61,765 research outputs from this source. They typically receive a little more attention than average, with a mean Attention Score of 6.8. This one is in the 6th percentile – i.e., 6% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 164,434 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 26th percentile – i.e., 26% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 565 others from the same source and published within six weeks on either side of this one. This one is in the 13th percentile – i.e., 13% of its contemporaries scored the same or lower than it.