Title |
Liquid-like pseudoelasticity of sub-10-nm crystalline silver particles
|
---|---|
Published in |
Nature Materials, October 2014
|
DOI | 10.1038/nmat4105 |
Pubmed ID | |
Authors |
Jun Sun, Longbing He, Yu-Chieh Lo, Tao Xu, Hengchang Bi, Litao Sun, Ze Zhang, Scott X. Mao, Ju Li |
Abstract |
In nanotechnology, small-volume metals with large surface area are used as electrodes, catalysts, interconnects and antennae. Their shape stability at room temperature has, however, been questioned. Using in situ high-resolution transmission electron microscopy, we find that Ag nanoparticles can be deformed like a liquid droplet but remain highly crystalline in the interior, with no sign of dislocation activity during deformation. Surface-diffusion-mediated pseudoelastic deformation is evident at room temperature, which can be driven by either an external force or capillary-energy minimization. Atomistic simulations confirm that such highly unusual Coble pseudoelasticity can indeed happen for sub-10-nm Ag particles at room temperature and at timescales from seconds to months. |
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Geographical breakdown
Country | Count | As % |
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United Kingdom | 2 | 15% |
Germany | 1 | 8% |
Netherlands | 1 | 8% |
France | 1 | 8% |
United States | 1 | 8% |
Unknown | 7 | 54% |
Demographic breakdown
Type | Count | As % |
---|---|---|
Members of the public | 7 | 54% |
Scientists | 5 | 38% |
Science communicators (journalists, bloggers, editors) | 1 | 8% |
Mendeley readers
Geographical breakdown
Country | Count | As % |
---|---|---|
United States | 3 | 1% |
Sweden | 1 | <1% |
United Kingdom | 1 | <1% |
Germany | 1 | <1% |
China | 1 | <1% |
Canada | 1 | <1% |
Japan | 1 | <1% |
Korea, Republic of | 1 | <1% |
Unknown | 262 | 96% |
Demographic breakdown
Readers by professional status | Count | As % |
---|---|---|
Student > Ph. D. Student | 86 | 32% |
Researcher | 40 | 15% |
Professor > Associate Professor | 23 | 8% |
Student > Master | 22 | 8% |
Student > Doctoral Student | 19 | 7% |
Other | 45 | 17% |
Unknown | 37 | 14% |
Readers by discipline | Count | As % |
---|---|---|
Materials Science | 79 | 29% |
Chemistry | 42 | 15% |
Engineering | 40 | 15% |
Physics and Astronomy | 30 | 11% |
Chemical Engineering | 8 | 3% |
Other | 15 | 6% |
Unknown | 58 | 21% |