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Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium

Overview of attention for article published in Journal of the American Chemical Society, November 2013
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Title
Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium
Published in
Journal of the American Chemical Society, November 2013
DOI 10.1021/ja409764j
Pubmed ID
Authors

Markus G. Scheibel, Yanlin Wu, A. Claudia Stückl, Lennard Krause, Elena Carl, Dietmar Stalke, Bas de Bruin, Sven Schneider

Abstract

Irradiation of rhodium(II) azido complex [Rh(N3){N(CHCHPtBu2)2}] allowed for the spectroscopic characterization of the first reported rhodium complex with a terminal nitrido ligand. DFT computations reveal that the unpaired electron of rhodium(IV) nitride complex [Rh(N){N(CHCHPtBu2)2}] is located in an antibonding Rh-N π* bond involving the nitrido moiety, thus resulting in predominant N-radical character, in turn providing a rationale for its transient nature and observed nitride coupling to dinitrogen.

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The data shown below were collected from the profiles of 2 X users who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 89 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Netherlands 2 2%
United States 1 1%
Korea, Republic of 1 1%
Unknown 85 96%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 24 27%
Researcher 15 17%
Student > Bachelor 11 12%
Student > Master 10 11%
Student > Doctoral Student 8 9%
Other 12 13%
Unknown 9 10%
Readers by discipline Count As %
Chemistry 74 83%
Chemical Engineering 1 1%
Physics and Astronomy 1 1%
Design 1 1%
Unknown 12 13%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 2. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 19 November 2013.
All research outputs
#14,182,545
of 22,731,677 outputs
Outputs from Journal of the American Chemical Society
#53,985
of 61,858 outputs
Outputs of similar age
#173,227
of 302,168 outputs
Outputs of similar age from Journal of the American Chemical Society
#321
of 490 outputs
Altmetric has tracked 22,731,677 research outputs across all sources so far. This one is in the 35th percentile – i.e., 35% of other outputs scored the same or lower than it.
So far Altmetric has tracked 61,858 research outputs from this source. They typically receive a little more attention than average, with a mean Attention Score of 6.8. This one is in the 11th percentile – i.e., 11% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 302,168 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 40th percentile – i.e., 40% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 490 others from the same source and published within six weeks on either side of this one. This one is in the 31st percentile – i.e., 31% of its contemporaries scored the same or lower than it.