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Hydrogen‐Bond‐Assisted Activation of Allylic Alcohols for Palladium‐Catalyzed Coupling Reactions

Overview of attention for article published in ChemSusChem, January 2014
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Title
Hydrogen‐Bond‐Assisted Activation of Allylic Alcohols for Palladium‐Catalyzed Coupling Reactions
Published in
ChemSusChem, January 2014
DOI 10.1002/cssc.201300723
Pubmed ID
Authors

Yasemin Gumrukcu, Bas de Bruin, Joost N. H. Reek

Abstract

We report direct activation of allylic alcohols using a hydrogen-bond-assisted palladium catalyst and use this for alkylation and amination reactions. The novel catalyst comprises a palladium complex based on a functionalized monodentate phosphoramidite ligand in combination with urea additives and affords linear alkylated and aminated allylic products selectively. Detailed kinetic analysis show that oxidative addition of the allyl alcohol is the rate-determining step, which is facilitated by hydrogen bonds between the alcohol, the ligand functional group, and the additional urea additive.

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 30 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Netherlands 2 7%
United States 1 3%
Unknown 27 90%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 6 20%
Student > Master 4 13%
Researcher 4 13%
Professor 4 13%
Professor > Associate Professor 3 10%
Other 2 7%
Unknown 7 23%
Readers by discipline Count As %
Chemistry 19 63%
Pharmacology, Toxicology and Pharmaceutical Science 1 3%
Unknown 10 33%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 24 January 2014.
All research outputs
#16,744,582
of 24,629,540 outputs
Outputs from ChemSusChem
#2,667
of 5,636 outputs
Outputs of similar age
#198,807
of 315,524 outputs
Outputs of similar age from ChemSusChem
#34
of 61 outputs
Altmetric has tracked 24,629,540 research outputs across all sources so far. This one is in the 21st percentile – i.e., 21% of other outputs scored the same or lower than it.
So far Altmetric has tracked 5,636 research outputs from this source. They receive a mean Attention Score of 3.4. This one is in the 48th percentile – i.e., 48% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 315,524 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 27th percentile – i.e., 27% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 61 others from the same source and published within six weeks on either side of this one. This one is in the 36th percentile – i.e., 36% of its contemporaries scored the same or lower than it.