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An Isolated Nitridyl Radical‐Bridged {Rh(N.)Rh} Complex

Overview of attention for article published in Angewandte Chemie. International Edition, May 2014
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Title
An Isolated Nitridyl Radical‐Bridged {Rh(N.)Rh} Complex
Published in
Angewandte Chemie. International Edition, May 2014
DOI 10.1002/anie.201403445
Pubmed ID
Authors

Yann Gloaguen, Christophe Rebreyend, Martin Lutz, Pravin Kumar, Martina Huber, Jarl Ivar van der Vlugt, Sven Schneider, Bas de Bruin

Abstract

Photochemical activation of [(PNNH)Rh(N3)] (PNNH = 6-di-(tert-butyl)phosphinomethyl-2,2'-bipyridine) complex 2 produced the paramagnetic (S = 1/2), [(PNN)Rh=N(·)-Rh(PNN)] complex 3 (PNN(-) = methylene-deprotonated PNNH), which could be crystallographically characterized. Spectroscopic investigation of 3 indicates a predominant nitridyl radical ((·)N(2-)) character, which was confirmed computationally. Complex 3 reacts selectively with CO, producing two equivalents of [(PNN)Rh(I)(CO)] complex 4, presumably by nitridyl radical N,N-coupling.

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X Demographics

The data shown below were collected from the profile of 1 X user who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 62 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Netherlands 2 3%
Germany 1 2%
France 1 2%
Korea, Republic of 1 2%
Japan 1 2%
United States 1 2%
Unknown 55 89%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 23 37%
Researcher 10 16%
Student > Master 8 13%
Student > Bachelor 6 10%
Student > Doctoral Student 4 6%
Other 8 13%
Unknown 3 5%
Readers by discipline Count As %
Chemistry 54 87%
Chemical Engineering 1 2%
Design 1 2%
Unknown 6 10%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 19 May 2014.
All research outputs
#22,758,309
of 25,371,288 outputs
Outputs from Angewandte Chemie. International Edition
#45,795
of 49,982 outputs
Outputs of similar age
#208,183
of 240,997 outputs
Outputs of similar age from Angewandte Chemie. International Edition
#568
of 688 outputs
Altmetric has tracked 25,371,288 research outputs across all sources so far. This one is in the 1st percentile – i.e., 1% of other outputs scored the same or lower than it.
So far Altmetric has tracked 49,982 research outputs from this source. They typically receive more attention than average, with a mean Attention Score of 7.8. This one is in the 1st percentile – i.e., 1% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 240,997 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 1st percentile – i.e., 1% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 688 others from the same source and published within six weeks on either side of this one. This one is in the 1st percentile – i.e., 1% of its contemporaries scored the same or lower than it.