↓ Skip to main content

Metastability Limit for the Nucleation of NaCl Crystals in Confinement

Overview of attention for article published in The Journal of Physical Chemistry Letters, February 2014
Altmetric Badge

Mentioned by

facebook
1 Facebook page

Citations

dimensions_citation
96 Dimensions

Readers on

mendeley
148 Mendeley
You are seeing a free-to-access but limited selection of the activity Altmetric has collected about this research output. Click here to find out more.
Title
Metastability Limit for the Nucleation of NaCl Crystals in Confinement
Published in
The Journal of Physical Chemistry Letters, February 2014
DOI 10.1021/jz500090x
Pubmed ID
Authors

Julie Desarnaud, Hannelore Derluyn, Jan Carmeliet, Daniel Bonn, Noushine Shahidzadeh

Abstract

We study the spontaneous nucleation and growth of sodium chloride crystals induced by controlled evaporation in confined geometries (microcapillaries) spanning several orders of magnitude in volume. In all experiments, the nucleation happens reproducibly at a very high supersaturation S ∼ 1.6 and is independent of the size, shape, and surface properties of the microcapillary. We show from classical nucleation theory that this is expected: S ∼ 1.6 corresponds to the point where nucleation first becomes observable on experimental time scales. A consequence of the high supersaturations reached at the onset of nucleation is the very rapid growth of a single skeletal (Hopper) crystal. Experiments on porous media also reveal the formation of Hopper crystals in the entrapped liquid pockets in the porous network and consequently underline the fact that sodium chloride can easily reach high supersaturations, in spite of what is commonly assumed for this salt.

Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 148 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
United States 1 <1%
France 1 <1%
Unknown 146 99%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 45 30%
Student > Master 21 14%
Researcher 20 14%
Professor 10 7%
Student > Doctoral Student 7 5%
Other 21 14%
Unknown 24 16%
Readers by discipline Count As %
Engineering 32 22%
Physics and Astronomy 18 12%
Chemistry 17 11%
Earth and Planetary Sciences 12 8%
Chemical Engineering 12 8%
Other 25 17%
Unknown 32 22%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 20 May 2014.
All research outputs
#22,760,732
of 25,377,790 outputs
Outputs from The Journal of Physical Chemistry Letters
#7,613
of 10,169 outputs
Outputs of similar age
#209,015
of 238,950 outputs
Outputs of similar age from The Journal of Physical Chemistry Letters
#72
of 86 outputs
Altmetric has tracked 25,377,790 research outputs across all sources so far. This one is in the 1st percentile – i.e., 1% of other outputs scored the same or lower than it.
So far Altmetric has tracked 10,169 research outputs from this source. They receive a mean Attention Score of 4.9. This one is in the 1st percentile – i.e., 1% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 238,950 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 1st percentile – i.e., 1% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 86 others from the same source and published within six weeks on either side of this one. This one is in the 1st percentile – i.e., 1% of its contemporaries scored the same or lower than it.