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Selective P 4 activation by an organometallic nickel( i ) radical: formation of a dinuclear nickel( ii ) tetraphosphide and related di- and trichalcogenides

Overview of attention for article published in Chemical Communications, January 2014
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Title
Selective P 4 activation by an organometallic nickel( i ) radical: formation of a dinuclear nickel( ii ) tetraphosphide and related di- and trichalcogenides
Published in
Chemical Communications, January 2014
DOI 10.1039/c4cc02601b
Pubmed ID
Authors

Stefan Pelties, Dirk Herrmann, Bas de Bruin, František Hartl, Robert Wolf

Abstract

The reaction of the 17e nickel(I) radical [CpNi(IDipp)] (1, IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with P4 results in a nickel tetraphosphide [{CpNi(IDipp)}2(μ-η(1):η(1)-P4)] with a butterfly-P4(2-) ligand; related chalcogenides [{CpNi(IDipp)}2(μ-E2)] (E = S, Se, Te) and [{CpNi(IDipp)}2(μ-E3)] (E = S, Se) are formed with S8, Se∞ and Te∞.

Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 48 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
United States 1 2%
Unknown 47 98%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 13 27%
Researcher 8 17%
Student > Master 7 15%
Student > Bachelor 6 13%
Professor > Associate Professor 2 4%
Other 5 10%
Unknown 7 15%
Readers by discipline Count As %
Chemistry 36 75%
Unspecified 1 2%
Unknown 11 23%