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X Demographics
Mendeley readers
Attention Score in Context
| Title |
Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex
|
|---|---|
| Published in |
Journal of the American Chemical Society, June 2014
|
| DOI | 10.1021/ja502164f |
| Pubmed ID | |
| Authors |
Daniël L. J. Broere, Bas de Bruin, Joost N. H. Reek, Martin Lutz, Sebastian Dechert, Jarl Ivar van der Vlugt |
| Abstract |
Coordination of the redox-active tridentate NNO ligand L(H2) to Pd(II) yields the paramagnetic iminobenzosemiquinonato complex 3. Single-electron reduction of 3 yields diamagnetic amidophenolato complex 4, capable of activating aliphatic azide 5. Experimental and computational studies suggest a redox-noninnocent pathway wherein the redox-active ligand facilitates intramolecular ligand-to-substrate single-electron transfer to generate an open-shell singlet "nitrene-substrate radical, ligand radical", enabling subsequent radical-type C-H amination reactivity with Pd(II). |
X Demographics
The data shown below were collected from the profiles of 2 X users who shared this research output. Click here to find out more about how the information was compiled.
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Unknown | 2 | 100% |
Demographic breakdown
| Type | Count | As % |
|---|---|---|
| Members of the public | 1 | 50% |
| Scientists | 1 | 50% |
Mendeley readers
The data shown below were compiled from readership statistics for 142 Mendeley readers of this research output. Click here to see the associated Mendeley record.
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| France | 3 | 2% |
| Netherlands | 3 | 2% |
| Japan | 1 | <1% |
| Unknown | 135 | 95% |
Demographic breakdown
| Readers by professional status | Count | As % |
|---|---|---|
| Student > Ph. D. Student | 36 | 25% |
| Student > Master | 26 | 18% |
| Researcher | 20 | 14% |
| Student > Bachelor | 19 | 13% |
| Student > Doctoral Student | 9 | 6% |
| Other | 16 | 11% |
| Unknown | 16 | 11% |
| Readers by discipline | Count | As % |
|---|---|---|
| Chemistry | 117 | 82% |
| Materials Science | 3 | 2% |
| Arts and Humanities | 1 | <1% |
| Physics and Astronomy | 1 | <1% |
| Pharmacology, Toxicology and Pharmaceutical Science | 1 | <1% |
| Other | 2 | 1% |
| Unknown | 17 | 12% |
Attention Score in Context
This research output has an Altmetric Attention Score of 10. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 16 April 2021.
All research outputs
#3,169,353
of 22,757,541 outputs
Outputs from Journal of the American Chemical Society
#9,561
of 61,912 outputs
Outputs of similar age
#32,890
of 228,185 outputs
Outputs of similar age from Journal of the American Chemical Society
#94
of 494 outputs
Altmetric has tracked 22,757,541 research outputs across all sources so far. Compared to these this one has done well and is in the 86th percentile: it's in the top 25% of all research outputs ever tracked by Altmetric.
So far Altmetric has tracked 61,912 research outputs from this source. They typically receive a little more attention than average, with a mean Attention Score of 6.8. This one has done well, scoring higher than 84% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 228,185 tracked outputs that were published within six weeks on either side of this one in any source. This one has done well, scoring higher than 85% of its contemporaries.
We're also able to compare this research output to 494 others from the same source and published within six weeks on either side of this one. This one has done well, scoring higher than 80% of its contemporaries.