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@MoritzSenger @H2ASE_NEWS @Lenz_Group Hi again. I do not recall the IR spectrum for Ni-CO. You can find Ni-SCOred (https://t.co/112war0xDZ) where proximal cluster is reduced but only EPR for Ni-CO as you said.
Inhibition of the [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F by carbon monoxide: An FTIR and EPR spectroscopic study
Overview of attention for article published in BBA - Bioenergetics, November 2009