| Title |
Near‐Infrared Polymer Light‐Emitting Diodes Based on Low‐Energy Gap Oligomers Copolymerized into a High‐Gap Polymer Host
|
|---|---|
| Published in |
Macromolecular Rapid Communications, April 2013
|
| DOI | 10.1002/marc.201300240 |
| Pubmed ID | |
| Authors |
Timothy T. Steckler, Oliver Fenwick, Toby Lockwood, Mats R. Andersson, Franco Cacialli |
| Abstract |
Near-infrared (NIR) polymer light-emitting diodes (PLEDs) based on a fluorene-dioctyloxyphenylene wide-gap host material copolymerized with a low-gap emitter are presented. Various loadings (1, 2.5, 10, 20 mol%) of the low-gap emitter are studied, with higher loadings leading to decreased efficiencies likely due to aggregation effects. While the 10 mol% loading resulted in almost pure NIR emission (>99.6%), the 1 mol% loading yielded optimum device performance, which is among the best reported to date for a unblended single-layer pure polymer emitter, with an external quantum efficiencies of 0.04% emitting at 909 nm. The high spectral purity of the PLEDs combined with their performance support the methodology of copolymerization as an effective strategy for developing NIR PLEDs. |
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