The outcome of 1:1 reactions of the tetranuclear 3d-4f Single Molecule Magnet (SMM) [Cu3Tb(L(Pr))(NO3)2(H2O)]NO3 (1) with (TBA)3[W(CN)8] (TBA = tri-n-butyl ammonium cation, [(n-Bu)3N-H](+)) in dimethylformamide (DMF) is dependent on the crystallization method employed: liquid-liquid diffusion of the reagents together gives {[Cu3Tb(L(Pr))W(CN)8(DMF)4]·(DMF)}n (2) whereas diethyl ether vapor diffusion into the reaction solution gives {[Cu3Tb(L(Pr))W(CN)8(DMF)3(H2O)3]·(DMF)1.5·(H2O)0.5}n (3). Both compounds are obtained as black single crystals and feature one-dimensional (1D) coordination networks (chains) of [1](3+) macrocycles linked by [W(CN)8](3-) anions. The two assemblies differ from a structural point of view. Complex 2 has a stepped arrangement with the linkers bound to the opposite faces of the macrocycle, whereas 3 has a square-wave arrangement due to the linkers binding to the same face of the macrocycle. Both compounds display an antiferromagnetic ground state below 3.5 and 2.4 K with a metamagnetic and antiferromagnetic (T, H) phase diagram for 2 and 3, respectively. Remarkably the slow dynamics of the magnetization of the [1](3+) macrocycle units is preserved in 3 while this property is quenched in 2 because of stronger intra- and interchain magnetic interactions inducing a higher critical temperature.
This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 13 November 2013.
All research outputs
#15,284,663
of 22,729,647 outputs
Outputs from Inorganic Chemistry
#13,683
of 21,571 outputs
Outputs of similar age
#130,421
of 212,391 outputs
Outputs of similar age from Inorganic Chemistry
#118
of 414 outputs
Altmetric has tracked 22,729,647 research outputs across all sources so far. This one is in the 22nd percentile – i.e., 22% of other outputs scored the same or lower than it.
So far Altmetric has tracked 21,571 research outputs from this source. They receive a mean Attention Score of 2.8. This one is in the 21st percentile – i.e., 21% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 212,391 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 28th percentile – i.e., 28% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 414 others from the same source and published within six weeks on either side of this one. This one is in the 2nd percentile – i.e., 2% of its contemporaries scored the same or lower than it.
