| Title |
An Integrated Photoelectrochemical–Chemical Loop for Solar‐Driven Overall Splitting of Hydrogen Sulfide
|
|---|---|
| Published in |
Angewandte Chemie. International Edition, March 2014
|
| DOI | 10.1002/anie.201400571 |
| Pubmed ID | |
| Authors | |
| Abstract |
Abundant and toxic hydrogen sulfide (H2 S) from industry and nature has been traditionally considered a liability. However, it represents a potential resource if valuable H2 and elemental sulfur can be simultaneously extracted through a H2 S splitting reaction. Herein a photochemical-chemical loop linked by redox couples such as Fe(2+) /Fe(3+) and I(-) /I3 (-) for photoelectrochemical H2 production and H2 S chemical absorption redox reactions are reported. Using functionalized Si as photoelectrodes, H2 S was successfully split into elemental sulfur and H2 with high stability and selectivity under simulated solar light. This new conceptual design will not only provide a possible route for using solar energy to convert H2 S into valuable resources, but also sheds light on some challenging photochemical reactions such as CH4 activation and CO2 reduction. |
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X Demographics
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Germany | 1 | 100% |
Demographic breakdown
| Type | Count | As % |
|---|---|---|
| Scientists | 1 | 100% |
Mendeley demographics
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Burkina Faso | 1 | 1% |
| Unknown | 97 | 99% |
Demographic breakdown
| Readers by professional status | Count | As % |
|---|---|---|
| Student > Ph. D. Student | 22 | 22% |
| Researcher | 16 | 16% |
| Student > Master | 13 | 13% |
| Professor | 8 | 8% |
| Student > Bachelor | 7 | 7% |
| Other | 15 | 15% |
| Unknown | 17 | 17% |
| Readers by discipline | Count | As % |
|---|---|---|
| Chemistry | 44 | 45% |
| Materials Science | 11 | 11% |
| Environmental Science | 6 | 6% |
| Engineering | 4 | 4% |
| Biochemistry, Genetics and Molecular Biology | 3 | 3% |
| Other | 9 | 9% |
| Unknown | 21 | 21% |