Reaction of [NBu4][LCu(II)OH] with excess ROOH (R = cumyl or tBu) yielded [NBu4][LCu(II)OOR], the reversible one-electron oxidation of which generated novel species with [CuOOR](2+) cores (formally Cu(III)OOR), identified by spectroscopy and theory for the case R = cumyl. This species reacts with weak O-H bonds in TEMPO-H and 4-dimethylaminophenol ((NMe2)PhOH), the latter yielding LCu(OPh(NMe2)), which was also prepared independently. With the identification of [CuOOR](2+) complexes, the first precedent for this core in enzymes is provided, with implications for copper monooxygenase mechanisms.
This research output has an Altmetric Attention Score of 3. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 20 July 2017.
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#13,510,607
of 24,140,950 outputs
Outputs from Journal of the American Chemical Society
#53,501
of 64,171 outputs
Outputs of similar age
#147,798
of 318,560 outputs
Outputs of similar age from Journal of the American Chemical Society
#360
of 545 outputs
Altmetric has tracked 24,140,950 research outputs across all sources so far. This one is in the 43rd percentile – i.e., 43% of other outputs scored the same or lower than it.
So far Altmetric has tracked 64,171 research outputs from this source. They typically receive a little more attention than average, with a mean Attention Score of 7.0. This one is in the 16th percentile – i.e., 16% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 318,560 tracked outputs that were published within six weeks on either side of this one in any source. This one has gotten more attention than average, scoring higher than 53% of its contemporaries.
We're also able to compare this research output to 545 others from the same source and published within six weeks on either side of this one. This one is in the 34th percentile – i.e., 34% of its contemporaries scored the same or lower than it.
