Keith E. Schilling, Sea‐Won Kim, Christopher S. Jones, Calvin F. Wolter

Phosphorus (P) is delivered to streams as episodic particulate P and more continuous soluble P (orthophosphorus [OP]), and it is important to determine the proportion of each P form in river water to more effectively design remedial measures. In this study, we evaluated the annual mean ratios of OP to total P (TP) concentrations and loads in 12 Iowa rivers and found systematic variation in the ratios. The OP/TP ratios were >60% in two tile-drained watersheds of the Des Moines Lobe and in a shallow fractured bedrock watershed in northeast Iowa, whereas in southern and western Iowa, OP contributions to TP were <30%. Higher OP/TP ratios were associated with greater row crop intensity in the watershed and a greater proportion of baseflow in the river. Orthophosphorus contributions from croplands would be greater in watersheds characterized by widespread tile drainage and well-drained soils, whereas cropland TP export would be dominated by particulate P in dissected till plains with poorly drained soils. Understanding the dominant form and transport pathway of P from agricultural areas in a watershed is seen as an important first step in determining appropriate conservation practices to reduce P loads.