Heteroleptic complexes [Fe(bpte)(bim)]X2 and [Fe(bpte)(xbim)]X2 (bpte = S,S'-bis(2-pyridylmethyl)-1,2-thioethane, bim = 2,2'-biimidazole, xbim = 1,1'-(α,α'-o-xylyl)-2,2'-biimidazole, X = ClO4(-), BF4(-), OTf(-)) were prepared by reacting the corresponding Fe(II) salts with a 1:1 mixture of the ligands. All mononuclear complexes exhibit temperature-induced spin crossover (SCO) with the onset above room temperature. The SCO is rather gradual, due to low cooperativity of interactions between the cationic complexes, as revealed by crystal structure analyses. These complexes expand the range of the recently discovered Fe(II) SCO materials with {N4S2} coordination environment.
This research output has an Altmetric Attention Score of 3. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 01 September 2017.
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#12,992,364
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Outputs of similar age from Inorganic Chemistry
#75
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Altmetric has tracked 22,999,744 research outputs across all sources so far. This one is in the 43rd percentile – i.e., 43% of other outputs scored the same or lower than it.
So far Altmetric has tracked 21,800 research outputs from this source. They receive a mean Attention Score of 2.8. This one has gotten more attention than average, scoring higher than 55% of its peers.
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We're also able to compare this research output to 342 others from the same source and published within six weeks on either side of this one. This one has done well, scoring higher than 77% of its contemporaries.
