Title |
Evidence of Coupled Carbon and Iron Cycling at a Hydrocarbon-Contaminated Site from Time Lapse Magnetic Susceptibility
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Published in |
Environmental Science & Technology, September 2017
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DOI | 10.1021/acs.est.7b02155 |
Pubmed ID | |
Authors |
Anders L. Lund, Lee D. Slater, Estella A. Atekwana, Dimitrios Ntarlagiannis, Isabelle Cozzarelli, Barbara A. Bekins |
Abstract |
Conventional characterization and monitoring of hydrocarbon (HC) pollution is often expensive and time consuming. Magnetic susceptibility (MS) has been proposed as an inexpensive, longterm monitoring proxy of the degradation of HC. We acquired repeated down hole MS logging data in boreholes at a HC contaminated field research site in Bemidji, MN, USA. The MS data were analyzed in conjunction with redox conditions and iron availability within the source zone in order to better assess whether MS can serve as a proxy for monitoring HC contamination in unconsolidated sediments. The MS response at the site diminished during the sampling period, which was found to coincide with depletion of solid phase iron in the source zone. Previous geochemical observations and modeling at the site suggest that the most likely cause of the decrease in MS is the transformation of magnetite to siderite, coupled with the exhaustion of ferrihydrite. Although the temporal MS response at this site gives valuable field-scale evidence for changing conditions of iron cycling and stability of iron minerals it does not provide a simple proxy for longterm monitoring of biodegradation of hydrocarbons in the smear zone. |
Mendeley readers
Geographical breakdown
Country | Count | As % |
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Unknown | 35 | 100% |
Demographic breakdown
Readers by professional status | Count | As % |
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Student > Master | 7 | 20% |
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Researcher | 5 | 14% |
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Professor | 2 | 6% |
Other | 4 | 11% |
Unknown | 8 | 23% |
Readers by discipline | Count | As % |
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Other | 6 | 17% |
Unknown | 9 | 26% |