| Title |
Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework
|
|---|---|
| Published in |
Nature Communications, December 2017
|
| DOI | 10.1038/s41467-017-02215-7 |
| Pubmed ID | |
| Authors |
Evandro Castaldelli, K. D. G. Imalka Jayawardena, David C. Cox, Guy J. Clarkson, Richard I. Walton, Long Le-Quang, Jerôme Chauvin, S. Ravi P. Silva, Grégoire Jean-François Demets |
| Abstract |
Metal-organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components according to desired applications. Despite the wide interest in and many potential applications of MOFs, such as in gas storage, catalysis, sensing and drug delivery, electrical semiconductivity and its control is still rare. The use and fabrication of electronic devices with MOF-based components has not been widely explored, despite significant progress of these components made in recent years. Here we report the synthesis and properties of a new highly crystalline, electrochemically active, cobalt and naphthalene diimide-based MOF that is an efficient electrical semiconductor and has a broad absorption spectrum, from 300 to 2500 nm. Its semiconductivity was determined by direct voltage bias using a four-point device, and it features a wavelength dependant photoconductive-photoresistive dual behaviour, with a very high responsivity of 2.5 × 105 A W-1. |
Login to access the Attention Digest and the Sentiment Analysis related to this output.
X Demographics
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Unknown | 2 | 100% |
Demographic breakdown
| Type | Count | As % |
|---|---|---|
| Members of the public | 2 | 100% |
Mendeley demographics
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Unknown | 86 | 100% |
Demographic breakdown
| Readers by professional status | Count | As % |
|---|---|---|
| Student > Ph. D. Student | 20 | 23% |
| Researcher | 9 | 10% |
| Student > Master | 8 | 9% |
| Other | 7 | 8% |
| Student > Bachelor | 7 | 8% |
| Other | 15 | 17% |
| Unknown | 20 | 23% |
| Readers by discipline | Count | As % |
|---|---|---|
| Chemistry | 39 | 45% |
| Materials Science | 6 | 7% |
| Chemical Engineering | 4 | 5% |
| Biochemistry, Genetics and Molecular Biology | 4 | 5% |
| Agricultural and Biological Sciences | 2 | 2% |
| Other | 6 | 7% |
| Unknown | 25 | 29% |