Control of Diastereoselectivity in Tandem Asymmetric Reactions Generating Nonadjacent Stereocenters with Bifunctional Catalysis by Cinchona Alkaloids

Overview of attention for article published in Journal of the American Chemical Society, January 2007

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氢键催化是一种依赖于氢键相互作用加速和控制有机反应的有机催化. 生物系统中，无论是在底物分子的定向还是在降低反应壁垒方面，氢键在诸多酶促反应里都起着关键的作用. 而化学方面直到最近才开始尝试利用氢键进行催化，与路易斯酸催化的研究相比，该领域尚且不发达.

Hydrogen bond catalysis is a type of organocatalysis that relies on use of hydrogen bonding interactions to accelerate and control organic reactions.

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