| Title |
Synthesis of Carbon/Sulfur Nanolaminates by Electrochemical Extraction of Titanium from Ti2SC
|
|---|---|
| Published in |
Angewandte Chemie. International Edition, February 2015
|
| DOI | 10.1002/anie.201500110 |
| Pubmed ID | |
| Authors | |
| Abstract |
Herein we electrochemically and selectively extract Ti from the MAX phase Ti2 SC to form carbon/sulfur (C/S) nanolaminates at room temperature. The products are composed of multi-layers of C/S flakes, with predominantly amorphous and some graphene-like structures. Covalent bonding between C and S is observed in the nanolaminates, which render the latter promising candidates as electrode materials for Li-S batteries. We also show that it is possible to extract Ti from other MAX phases, such as Ti3 AlC2 , Ti3 SnC2 , and Ti2 GeC, suggesting that electrochemical etching can be a powerful method to selectively extract the "M" elements from the MAX phases, to produce "AX" layered structures, that cannot be made otherwise. The latter hold promise for a variety of applications, such as energy storage, catalysis, etc. |
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X Demographics
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Germany | 1 | 50% |
| Unknown | 1 | 50% |
Demographic breakdown
| Type | Count | As % |
|---|---|---|
| Scientists | 2 | 100% |
Mendeley demographics
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| United States | 1 | <1% |
| Poland | 1 | <1% |
| Iran, Islamic Republic of | 1 | <1% |
| Germany | 1 | <1% |
| Unknown | 127 | 97% |
Demographic breakdown
| Readers by professional status | Count | As % |
|---|---|---|
| Student > Ph. D. Student | 28 | 21% |
| Researcher | 22 | 17% |
| Student > Bachelor | 9 | 7% |
| Professor | 8 | 6% |
| Student > Postgraduate | 8 | 6% |
| Other | 29 | 22% |
| Unknown | 27 | 21% |
| Readers by discipline | Count | As % |
|---|---|---|
| Materials Science | 40 | 31% |
| Chemistry | 25 | 19% |
| Engineering | 12 | 9% |
| Energy | 7 | 5% |
| Chemical Engineering | 4 | 3% |
| Other | 7 | 5% |
| Unknown | 36 | 27% |