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Investigation of interactions in Lewis pairs between phosphines and boranes by analyzing crystal structures from the Cambridge Structural Database

Overview of attention for article published in ACTA CRYSTALLOGRAPHICA SECTION B, April 2018
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Title
Investigation of interactions in Lewis pairs between phosphines and boranes by analyzing crystal structures from the Cambridge Structural Database
Published in
ACTA CRYSTALLOGRAPHICA SECTION B, April 2018
DOI 10.1107/s2052520618003736
Pubmed ID
Authors

Milan M. Milovanović, Jelena M. Andrić, Vesna B. Medaković, Jean-Pierre Djukic, Snežana D. Zarić

Abstract

The interactions between phosphines and boranes in crystal structures have been investigated by analyzing data from the Cambridge Structural Database (CSD). The interactions between phosphines and boranes were classified into three types; two types depend on groups on the boron atom, whereas the third one involves frustrated Lewis pairs (FLPs). The data enabled geometric parameters in structures to be compared with phosphine-borane FLPs with classical Lewis pairs. Most of the crystal structures (78.1%) contain BH3 as the borane group. In these systems, the boron-phosphorus distance is shorter than systems where the boron atom is surrounded by groups other than hydrogen atoms. The analysis of the CSD data has shown that FLPs have a tendency for the longest boron-phosphorus distance among all phosphine-borane pairs, as well as different other geometrical parameters. The results show that most of the frustrated phosphine-borane pairs found in crystal structures are bridged ones. The minority of non-bridged FLP structures contain, beside phosphorus and boron atoms, other heteroatoms (O, N, S for instance).

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Mendeley readers

The data shown below were compiled from readership statistics for 7 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 7 100%

Demographic breakdown

Readers by professional status Count As %
Student > Bachelor 2 29%
Unspecified 1 14%
Student > Doctoral Student 1 14%
Other 1 14%
Student > Ph. D. Student 1 14%
Other 1 14%
Readers by discipline Count As %
Chemistry 5 71%
Pharmacology, Toxicology and Pharmaceutical Science 1 14%
Unspecified 1 14%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 02 November 2018.
All research outputs
#17,292,294
of 25,382,440 outputs
Outputs from ACTA CRYSTALLOGRAPHICA SECTION B
#1,353
of 2,139 outputs
Outputs of similar age
#219,597
of 339,945 outputs
Outputs of similar age from ACTA CRYSTALLOGRAPHICA SECTION B
#7
of 20 outputs
Altmetric has tracked 25,382,440 research outputs across all sources so far. This one is in the 21st percentile – i.e., 21% of other outputs scored the same or lower than it.
So far Altmetric has tracked 2,139 research outputs from this source. They receive a mean Attention Score of 2.8. This one is in the 30th percentile – i.e., 30% of its peers scored the same or lower than it.
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We're also able to compare this research output to 20 others from the same source and published within six weeks on either side of this one. This one is in the 1st percentile – i.e., 1% of its contemporaries scored the same or lower than it.