| Title |
Nanoporous Graphitic-C3N4@Carbon Metal-Free Electrocatalysts for Highly Efficient Oxygen Reduction
|
|---|---|
| Published in |
Journal of the American Chemical Society, November 2011
|
| DOI | 10.1021/ja209206c |
| Pubmed ID | |
| Authors | |
| Abstract |
Based on theoretical prediction, a g-C(3)N(4)@carbon metal-free oxygen reduction reaction (ORR) electrocatalyst was designed and synthesized by uniform incorporation of g-C(3)N(4) into a mesoporous carbon to enhance the electron transfer efficiency of g-C(3)N(4). The resulting g-C(3)N(4)@carbon composite exhibited competitive catalytic activity (11.3 mA cm(-2) kinetic-limiting current density at -0.6 V) and superior methanol tolerance compared to a commercial Pt/C catalyst. Furthermore, it demonstrated significantly higher catalytic efficiency (nearly 100% of four-electron ORR process selectivity) than a Pt/C catalyst. The proposed synthesis route is facile and low-cost, providing a feasible method for the development of highly efficient electrocatalysts. |
Login to access the Attention Digest and the Sentiment Analysis related to this output.
X Demographics
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Unknown | 1 | 100% |
Demographic breakdown
| Type | Count | As % |
|---|---|---|
| Scientists | 1 | 100% |
Mendeley demographics
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| China | 2 | <1% |
| United States | 1 | <1% |
| Ukraine | 1 | <1% |
| Singapore | 1 | <1% |
| Unknown | 319 | 98% |
Demographic breakdown
| Readers by professional status | Count | As % |
|---|---|---|
| Student > Ph. D. Student | 87 | 27% |
| Researcher | 39 | 12% |
| Student > Master | 32 | 10% |
| Student > Bachelor | 20 | 6% |
| Professor | 15 | 5% |
| Other | 42 | 13% |
| Unknown | 89 | 27% |
| Readers by discipline | Count | As % |
|---|---|---|
| Chemistry | 117 | 36% |
| Materials Science | 33 | 10% |
| Chemical Engineering | 23 | 7% |
| Engineering | 17 | 5% |
| Physics and Astronomy | 9 | 3% |
| Other | 21 | 6% |
| Unknown | 104 | 32% |