Graphitic carbon nitride (g-C₃N₄) and titanium dioxide (TiO₂) were chosen as a model system to investigate photocatalytic abilities of heterojunction system under UV and visible light conditions. The use of g-C₃N₄ has been shown to be effective in the reduction in recombination through the interaction between the two interfaces of TiO₂ and g-C₃N₄. A simple method of preparing g-C₃N₄ through the pyrolysis of melamine was employed, which was then added to undoped TiO₂ material to form the g-C₃N₄-TiO₂ system. These materials were then fully characterized by X-ray diffraction (XRD), Brunauer Emmett Teller (BET), and various spectroscopic techniques including Raman, X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), diffuse absorbance, and photoluminescence analysis. Photocatalysis studies were conducted using the model dye, rhodamine 6G utilizing visible and UV light irradiation. Raman spectroscopy confirmed that a composite of the materials was formed as opposed to a mixture of the two. Using XPS analysis, a shift in the nitrogen peak to that indicative of substitutional nitrogen was detected for all doped samples. This is then mirrored in the diffuse absorbance results, which show a clear decrease in band gap values for these samples, showing the effective band gap alteration achieved through this preparation process. When g-C₃N₄-TiO₂ samples were analyzed under visible light irradiation, no significant improvement was observed compared that of pure TiO₂. However, under UV light irradiation conditions, the photocatalytic ability of the doped samples exhibited an increased reactivity when compared to the undoped TiO₂ (0.130 min(-1)), with 4% g-C₃N₄-TiO₂ (0.187 min(-1)), showing a 43.9% increase in reactivity. Further doping to 8% g-C₃N₄-TiO₂ lead to a decrease in reactivity against rhodamine 6G. BET analysis determined that the surface area of the 4% and 8% g-C₃N₄-TiO₂ samples were very similar, with values of 29.4 and 28.5 m²/g, respectively, suggesting that the actual surface area is not a contributing factor. This could be due to an overloading of the system with covering of the active sites resulting in a lower reaction rate. XPS analysis showed that surface hydroxyl radicals and oxygen vacancies are not being formed throughout this preparation. Therefore, it can be suggested that the increased photocatalytic reaction rates are due to successful interfacial interactions with the g-C₃N₄-doped TiO₂ systems.
This research output has an Altmetric Attention Score of 4. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 03 May 2024.
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#10,733,812
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#21
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Altmetric has tracked 33,510,145 research outputs across all sources so far. This one has received more attention than most of these and is in the 67th percentile.
So far Altmetric has tracked 13,938 research outputs from this source. They receive a mean Attention Score of 2.7. This one has done well, scoring higher than 84% of its peers.
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We're also able to compare this research output to 126 others from the same source and published within six weeks on either side of this one. This one has done well, scoring higher than 83% of its contemporaries.
