Title |
Binding of Mercury(II) to Dissolved Organic Matter: The Role of the Mercury-to-DOM Concentration Ratio
|
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Published in |
Environmental Science & Technology, July 2002
|
DOI | 10.1021/es025699i |
Pubmed ID | |
Authors |
Markus Haitzer, George R. Aiken, Joseph N. Ryan |
Abstract |
The binding of Hg(II) to dissolved organic matter (DOM; hydrophobic acids isolated from the Florida Everglades by XAD-8 resin) was measured at a wide range of Hg-to-DOM concentration ratios using an equilibrium dialysis ligand exchange method. Conditional distribution coefficients (K(DOM)') determined by this method were strongly affected by the Hg/DOM concentration ratio. At Hg/DOM ratios below approximately 1 microg of Hg/mg of DOM, we observed very strong interactions (K(DOM)' = 10(23.2+/-1.0) L kg(-1) at pH = 7.0 and I = 0.1), indicative of mercury-thiol bonds. Hg/DOM ratios above approximately 10 microg of Hg/mg of DOM, as used in most studies that have determined Hg-DOM binding constants, gave much lower K(DOM)' values (10(10.7+/-1.0) L kg(-1) at pH = 4.9-5.6 and I = 0.1), consistent with Hg binding mainly to oxygen functional groups. These results suggest that the binding of Hg to DOM under natural conditions (very low Hg/DOM ratios) is controlled by a small fraction of DOM molecules containing a reactive thiol functional group. Therefore, Hg/DOM distribution coefficients used for modeling the biogeochemical behavior of Hg in natural systems need to be determined at low Hg/DOM ratios. |
Mendeley readers
Geographical breakdown
Country | Count | As % |
---|---|---|
United States | 3 | 2% |
Canada | 2 | 1% |
Brazil | 1 | <1% |
Argentina | 1 | <1% |
Portugal | 1 | <1% |
Unknown | 191 | 96% |
Demographic breakdown
Readers by professional status | Count | As % |
---|---|---|
Student > Ph. D. Student | 51 | 26% |
Researcher | 35 | 18% |
Student > Master | 23 | 12% |
Student > Doctoral Student | 16 | 8% |
Student > Bachelor | 11 | 6% |
Other | 29 | 15% |
Unknown | 34 | 17% |
Readers by discipline | Count | As % |
---|---|---|
Environmental Science | 64 | 32% |
Chemistry | 27 | 14% |
Agricultural and Biological Sciences | 20 | 10% |
Earth and Planetary Sciences | 17 | 9% |
Engineering | 15 | 8% |
Other | 10 | 5% |
Unknown | 46 | 23% |