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Mesoscopic architectures of porous coordination polymers fabricated by pseudomorphic replication

Overview of attention for article published in Nature Materials, June 2012
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About this Attention Score

  • In the top 25% of all research outputs scored by Altmetric
  • High Attention Score compared to outputs of the same age (95th percentile)
  • High Attention Score compared to outputs of the same age and source (80th percentile)

Mentioned by

news
1 news outlet
blogs
1 blog
twitter
1 X user
patent
7 patents
wikipedia
1 Wikipedia page

Readers on

mendeley
290 Mendeley
citeulike
1 CiteULike
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Title
Mesoscopic architectures of porous coordination polymers fabricated by pseudomorphic replication
Published in
Nature Materials, June 2012
DOI 10.1038/nmat3359
Pubmed ID
Authors

Julien Reboul, Shuhei Furukawa, Nao Horike, Manuel Tsotsalas, Kenji Hirai, Hiromitsu Uehara, Mio Kondo, Nicolas Louvain, Osami Sakata, Susumu Kitagawa

Abstract

The spatial organization of porous coordination polymer (PCP) crystals into higher-order structures is critical for their integration into separation systems, heterogeneous catalysts, ion/electron transport and photonic devices. Here, we demonstrate a rapid method to spatially control the nucleation site, leading to the formation of mesoscopic architecture made of PCPs, in both two and three dimensions. Inspired by geological processes, this method relies on the morphological replacement of a shaped sacrificial metal oxide used both as a metal source and as an 'architecture-directing agent' by an analogous PCP architecture. Spatiotemporal harmonization of the metal oxide dissolution and the PCP crystallization allowed the preservation of very fine mineral morphological details of periodic alumina inverse opal structures. The replication of randomly structured alumina aerogels resulted in a PCP architecture with hierarchical porosity in which the hydrophobic micropores of the PCP and the mesopores/macropores inherited from the parent aerogels synergistically enhanced the material's selectivity and mass transfer for water/ethanol separation.

X Demographics

X Demographics

The data shown below were collected from the profile of 1 X user who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 290 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
United Kingdom 3 1%
United States 3 1%
Germany 2 <1%
Canada 2 <1%
Belgium 2 <1%
Iran, Islamic Republic of 1 <1%
Mexico 1 <1%
India 1 <1%
Argentina 1 <1%
Other 2 <1%
Unknown 272 94%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 93 32%
Student > Master 39 13%
Researcher 37 13%
Student > Bachelor 21 7%
Professor > Associate Professor 15 5%
Other 45 16%
Unknown 40 14%
Readers by discipline Count As %
Chemistry 130 45%
Materials Science 41 14%
Engineering 24 8%
Chemical Engineering 15 5%
Physics and Astronomy 9 3%
Other 18 6%
Unknown 53 18%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 28. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 28 November 2023.
All research outputs
#1,348,664
of 24,946,857 outputs
Outputs from Nature Materials
#1,180
of 4,268 outputs
Outputs of similar age
#7,384
of 169,586 outputs
Outputs of similar age from Nature Materials
#10
of 45 outputs
Altmetric has tracked 24,946,857 research outputs across all sources so far. Compared to these this one has done particularly well and is in the 94th percentile: it's in the top 10% of all research outputs ever tracked by Altmetric.
So far Altmetric has tracked 4,268 research outputs from this source. They typically receive a lot more attention than average, with a mean Attention Score of 33.1. This one has gotten more attention than average, scoring higher than 72% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 169,586 tracked outputs that were published within six weeks on either side of this one in any source. This one has done particularly well, scoring higher than 95% of its contemporaries.
We're also able to compare this research output to 45 others from the same source and published within six weeks on either side of this one. This one has done well, scoring higher than 80% of its contemporaries.