| Title |
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
|
|---|---|
| Published in |
Journal of the American Chemical Society, August 2012
|
| DOI | 10.1021/ja3055639 |
| Pubmed ID | |
| Authors | |
| Abstract |
We have synthesized, characterized, and computationally simulated/validated the behavior of two new metal-organic framework (MOF) materials displaying the highest experimental Brunauer-Emmett-Teller (BET) surface areas of any porous materials reported to date (~7000 m(2)/g). Key to evacuating the initially solvent-filled materials without pore collapse, and thereby accessing the ultrahigh areas, is the use of a supercritical CO(2) activation technique. Additionally, we demonstrate computationally that by shifting from phenyl groups to "space efficient" acetylene moieties as linker expansion units, the hypothetical maximum surface area for a MOF material is substantially greater than previously envisioned (~14600 m(2)/g (or greater) versus ~10500 m(2)/g). |
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X Demographics
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Japan | 2 | 14% |
| Indonesia | 1 | 7% |
| United States | 1 | 7% |
| Spain | 1 | 7% |
| United Kingdom | 1 | 7% |
| Norway | 1 | 7% |
| Unknown | 7 | 50% |
Demographic breakdown
| Type | Count | As % |
|---|---|---|
| Members of the public | 10 | 71% |
| Scientists | 4 | 29% |
Mendeley demographics
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| United States | 13 | <1% |
| Germany | 8 | <1% |
| Canada | 3 | <1% |
| United Kingdom | 2 | <1% |
| Czechia | 2 | <1% |
| Switzerland | 2 | <1% |
| Belgium | 2 | <1% |
| Argentina | 2 | <1% |
| South Africa | 1 | <1% |
| Other | 5 | <1% |
| Unknown | 1952 | 98% |
Demographic breakdown
| Readers by professional status | Count | As % |
|---|---|---|
| Student > Ph. D. Student | 435 | 22% |
| Student > Master | 263 | 13% |
| Researcher | 185 | 9% |
| Student > Bachelor | 158 | 8% |
| Student > Doctoral Student | 90 | 5% |
| Other | 208 | 10% |
| Unknown | 653 | 33% |
| Readers by discipline | Count | As % |
|---|---|---|
| Chemistry | 790 | 40% |
| Chemical Engineering | 119 | 6% |
| Engineering | 114 | 6% |
| Materials Science | 111 | 6% |
| Physics and Astronomy | 25 | 1% |
| Other | 110 | 6% |
| Unknown | 723 | 36% |