Title |
Chemically Induced Electronic Excitations at Metal Surfaces
|
---|---|
Published in |
Science, December 2001
|
DOI | 10.1126/science.1066134 |
Pubmed ID | |
Authors |
Brian Gergen, Hermann Nienhaus, W. Henry Weinberg, Eric W. McFarland |
Abstract |
The energy released in low-energy chemisorption or physisorption of molecules on metal surfaces is usually expected to be dissipated by surface vibrations (phonons). Theoretical descriptions of competing electronic excitations are incomplete, and experimental observation of excited charge carriers has been difficult except at energies high enough to eject electrons from the surface. We observed reaction-induced electron excitations during gas interactions with polycrystalline silver for a variety of species with adsorption energies between 0.2 and 3.5 electron volts. The probability of exciting a detectable electron increases with increasing adsorption energy, and the measured time dependence of the electron current can be understood in terms of the strength and mechanism of adsorption. |
Mendeley readers
Geographical breakdown
Country | Count | As % |
---|---|---|
United States | 2 | 2% |
Germany | 1 | 1% |
Peru | 1 | 1% |
United Kingdom | 1 | 1% |
Spain | 1 | 1% |
Argentina | 1 | 1% |
Unknown | 87 | 93% |
Demographic breakdown
Readers by professional status | Count | As % |
---|---|---|
Student > Ph. D. Student | 30 | 32% |
Researcher | 16 | 17% |
Professor | 9 | 10% |
Professor > Associate Professor | 7 | 7% |
Student > Bachelor | 5 | 5% |
Other | 11 | 12% |
Unknown | 16 | 17% |
Readers by discipline | Count | As % |
---|---|---|
Chemistry | 37 | 39% |
Physics and Astronomy | 15 | 16% |
Engineering | 10 | 11% |
Materials Science | 10 | 11% |
Biochemistry, Genetics and Molecular Biology | 1 | 1% |
Other | 4 | 4% |
Unknown | 17 | 18% |