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Direct Imaging of Covalent Bond Structure in Single-Molecule Chemical Reactions

Overview of attention for article published in Science, May 2013
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About this Attention Score

  • In the top 5% of all research outputs scored by Altmetric
  • High Attention Score compared to outputs of the same age (99th percentile)
  • High Attention Score compared to outputs of the same age and source (99th percentile)

Readers on

mendeley
521 Mendeley
citeulike
4 CiteULike
Title
Direct Imaging of Covalent Bond Structure in Single-Molecule Chemical Reactions
Published in
Science, May 2013
DOI 10.1126/science.1238187
Pubmed ID
Authors

Dimas G. de Oteyza, Patrick Gorman, Yen-Chia Chen, Sebastian Wickenburg, Alexander Riss, Duncan J. Mowbray, Grisha Etkin, Zahra Pedramrazi, Hsin-Zon Tsai, Angel Rubio, Michael F. Crommie, Felix R. Fischer, de Oteyza, Dimas G, Gorman, Patrick, Chen, Yen-Chia, Wickenburg, Sebastian, Riss, Alexander, Mowbray, Duncan J, Etkin, Grisha, Pedramrazi, Zahra, Tsai, Hsin-Zon, Rubio, Angel, Crommie, Michael F, Fischer, Felix R, D. G. de Oteyza, P. Gorman, Y.-C. Chen, S. Wickenburg, A. Riss, D. J. Mowbray, G. Etkin, Z. Pedramrazi, H.-Z. Tsai, A. Rubio, M. F. Crommie, F. R. Fischer

Abstract

Observing the intricate chemical transformation of an individual molecule as it undergoes a complex reaction is a long-standing challenge in molecular imaging. Advances in scanning probe microscopy now provide the tools to visualize not only the frontier orbitals of chemical reaction partners and products, but their internal covalent bond configurations as well. We used noncontact atomic force microscopy to investigate reaction-induced changes in the detailed internal bond structure of individual oligo-(phenylene-1,2-ethynylenes) on a (100) oriented silver surface as they underwent a series of cyclization processes. Our images reveal the complex surface reaction mechanisms underlying thermally induced cyclization cascades of enediynes. Calculations using ab initio density functional theory provide additional support for the proposed reaction pathways.

Twitter Demographics

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Mendeley readers

The data shown below were compiled from readership statistics for 521 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Germany 15 3%
United States 13 2%
Japan 9 2%
United Kingdom 8 2%
Spain 6 1%
China 4 <1%
Netherlands 4 <1%
Switzerland 4 <1%
Brazil 2 <1%
Other 14 3%
Unknown 442 85%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 196 38%
Researcher 110 21%
Student > Master 53 10%
Professor > Associate Professor 41 8%
Student > Bachelor 32 6%
Other 89 17%
Readers by discipline Count As %
Chemistry 183 35%
Physics and Astronomy 134 26%
Agricultural and Biological Sciences 81 16%
Materials Science 39 7%
Engineering 26 5%
Other 58 11%

Attention Score in Context

This research output has an Altmetric Attention Score of 779. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 03 September 2017.
All research outputs
#4,207
of 9,708,560 outputs
Outputs from Science
#220
of 45,112 outputs
Outputs of similar age
#36
of 130,297 outputs
Outputs of similar age from Science
#4
of 714 outputs
Altmetric has tracked 9,708,560 research outputs across all sources so far. Compared to these this one has done particularly well and is in the 99th percentile: it's in the top 5% of all research outputs ever tracked by Altmetric.
So far Altmetric has tracked 45,112 research outputs from this source. They typically receive a lot more attention than average, with a mean Attention Score of 35.8. This one has done particularly well, scoring higher than 99% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 130,297 tracked outputs that were published within six weeks on either side of this one in any source. This one has done particularly well, scoring higher than 99% of its contemporaries.
We're also able to compare this research output to 714 others from the same source and published within six weeks on either side of this one. This one has done particularly well, scoring higher than 99% of its contemporaries.