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Highly enantioselective copper( i )-catalyzed conjugate addition of 1,3-diynes to α,β-unsaturated trifluoromethyl ketones

Overview of attention for article published in Chemical Communications, January 2015
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Title
Highly enantioselective copper( i )-catalyzed conjugate addition of 1,3-diynes to α,β-unsaturated trifluoromethyl ketones
Published in
Chemical Communications, January 2015
DOI 10.1039/c5cc01676b
Pubmed ID
Authors

Amparo Sanz-Marco, Gonzalo Blay, M. Carmen Muñoz, José R. Pedro

Abstract

The conjugate diynylation of α,β-unsaturated trifluoromethyl ketones is carried out in the presence of a low catalytic load (2.5 mol%) of a copper(i)-MeOBIPHEP complex, triethylamine and a terminal 1,3-diyne. Pre-metalation of the terminal 1,3-diyne with stoichiometric or higher amounts of dialkylzinc reagent is not required. The corresponding internal diynes bearing a propargylic stereogenic center are obtained with good yields and excellent enantioselectivities.

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X Demographics

The data shown below were collected from the profile of 1 X user who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 22 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Canada 1 5%
Unknown 21 95%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 6 27%
Researcher 4 18%
Student > Master 4 18%
Professor 2 9%
Student > Bachelor 2 9%
Other 0 0%
Unknown 4 18%
Readers by discipline Count As %
Chemistry 17 77%
Unknown 5 23%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 28 February 2017.
All research outputs
#20,407,586
of 22,957,478 outputs
Outputs from Chemical Communications
#18,882
of 21,389 outputs
Outputs of similar age
#296,801
of 354,004 outputs
Outputs of similar age from Chemical Communications
#1,052
of 1,271 outputs
Altmetric has tracked 22,957,478 research outputs across all sources so far. This one is in the 1st percentile – i.e., 1% of other outputs scored the same or lower than it.
So far Altmetric has tracked 21,389 research outputs from this source. They receive a mean Attention Score of 4.0. This one is in the 1st percentile – i.e., 1% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 354,004 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 1st percentile – i.e., 1% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 1,271 others from the same source and published within six weeks on either side of this one. This one is in the 1st percentile – i.e., 1% of its contemporaries scored the same or lower than it.