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Electrocatalytic Oxygen Evolution with an Immobilized TAML Activator

Overview of attention for article published in Journal of the American Chemical Society, April 2014
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  • Good Attention Score compared to outputs of the same age (75th percentile)
  • Above-average Attention Score compared to outputs of the same age and source (59th percentile)

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1 blog

Citations

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72 Dimensions

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80 Mendeley
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1 CiteULike
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Title
Electrocatalytic Oxygen Evolution with an Immobilized TAML Activator
Published in
Journal of the American Chemical Society, April 2014
DOI 10.1021/ja5015986
Pubmed ID
Authors

Ethan L. Demeter, Shayna L. Hilburg, Newell R. Washburn, Terrence J. Collins, John R. Kitchin

Abstract

Iron complexes of tetra-amido macrocyclic ligands are important members of the suite of oxidation catalysts known as TAML activators. TAML activators are known to be fast homogeneous water oxidation (WO) catalysts, producing oxygen in the presence of chemical oxidants, e.g., ceric ammonium nitrate. These homogeneous systems exhibited low turnover numbers (TONs). Here we demonstrate immobilization on glassy carbon and carbon paper in an ink composed of the prototype TAML activator, carbon black, and Nafion and the subsequent use of this composition in heterogeneous electrocatalytic WO. The immobilized TAML system is shown to readily produce O2 with much higher TONs than the homogeneous predecessors.

Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 80 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Mexico 1 1%
United States 1 1%
Unknown 78 98%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 30 38%
Researcher 15 19%
Student > Bachelor 7 9%
Student > Master 6 8%
Student > Doctoral Student 4 5%
Other 10 13%
Unknown 8 10%
Readers by discipline Count As %
Chemistry 56 70%
Environmental Science 3 4%
Engineering 3 4%
Chemical Engineering 2 3%
Materials Science 2 3%
Other 3 4%
Unknown 11 14%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 6. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 12 August 2016.
All research outputs
#5,730,092
of 22,753,345 outputs
Outputs from Journal of the American Chemical Society
#24,209
of 61,907 outputs
Outputs of similar age
#54,531
of 227,778 outputs
Outputs of similar age from Journal of the American Chemical Society
#210
of 520 outputs
Altmetric has tracked 22,753,345 research outputs across all sources so far. This one has received more attention than most of these and is in the 74th percentile.
So far Altmetric has tracked 61,907 research outputs from this source. They typically receive a little more attention than average, with a mean Attention Score of 6.8. This one has gotten more attention than average, scoring higher than 60% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 227,778 tracked outputs that were published within six weeks on either side of this one in any source. This one has done well, scoring higher than 75% of its contemporaries.
We're also able to compare this research output to 520 others from the same source and published within six weeks on either side of this one. This one has gotten more attention than average, scoring higher than 59% of its contemporaries.